《凹凸棒石氢氧化物纳米复合材料对磷的吸附热力学 THERMODYNAMIC OF ADSORBING PHOSPHATE FROM WATER ON PALYGORSKITE HYDRATE NANO-COMPOUND MATERIALS》.pdfVIP

第37卷第lO期 硅酸盐学报 V01．37，No．10 2009年l0月 JOURNALOFTHECHINESECERAMICSOCIETY October，2009 凹凸棒石／氢氧化物纳米复合材料对磷的吸附热力学 潘敏，陈天虎，黄晓鸣，庆承松，汪嘉源 (合肥工业大学资源与环境工程学院，合肥230009) 摘要：用铁／铝盐水解法制备了凹lnl棒石，铝氢氧化物(PNCM 石黏土纳米复合材料，对比研究了这3种复合材料和纯凹凸棒石黏士对水中磷的吸附净化能力，通过等温吸附实验探讨了3种纳米复合材料对磷的吸 附机理。结果表明：PNCM I和PNCMⅢ凹凸棒石黏十纳米复合材料对磷具有良好的吸附净化能力，而且温度对其影响很小；当初始浓度为1。2mg／L 和5mg，U以磷计)时，100mL水中加入0．I 的吸附是吸热的物理吸附过程。且都为熵增加的吸附过程。 关键词：凹凸棒石；吸附；磷；热力学 中图分类号：0615 文献标志码：A 文章编号：0454_5648(2009)10_1673_05 THERMoDYNAMICoFADSoRBINGPHoSPHATEFRoMⅥ，ATERoN HYDRATENANo．CoMPoUNDMATERIALS PAN Min，CHENTianhu,HUANG Xiaoming,QINGChengsong,WANGJiayuan of Resourcesand of (School Environmental，HefeiUniversityTechnology,Hefei230009，China) Abstract：The andmechanismsofthreekindsof nanometer adsorptioncapacities palygorskitecomposite hy． aluminumand-iron on IIand drate，iron l，PNCMPNCM hydrate，and hydrate)coatedpalygorskite(PNCM III)，andpurepalygor- skite are resultsdemonstratethatPNCMI andPNCMIllareableto remove adsorbingphosphateinvestigated．The effectively from donot toaffecttheremoval ofPNCMIandPNCMIH．The iso- phosphatesolution．TemperaturesaDpear effieiency adsorption thermsofthethreekindsof nanometer matcrialscouldbefittedto isotherms palygorskitecompound Langrnuir equation．Thephos- onPNCMIandPNCMⅢarc andendothermic．andthe andchemical phateadsorption spontaneous physicaladsorption adsorption coexist．PNCMII is andexhibits