《3,5-双(4-氨基苯氧基)苯甲酸的合成及其聚酰亚胺薄膜的性能研究》.pdfVIP

·lB· 3，5一双(4一氨基苯氧基)苯甲酸的合成及其 聚酰亚胺薄膜的性能研究 李恩1，虞鑫海1，徐永芬-，刘万章z (1．东华大学应用化学系。上海201620；2．浙江金鹏化工股份有限公司，浙江台州318050) 能；吸水性均小于3％，具有优异的疏水性能：其拉伸强度在15—56MPa之间。 关键词：3．5一双(4_氨基苯氧基)苯甲酸(35BAPBA)；含羧基聚酰亚胺；合成；性能研究 323．7 中图分类号：TQ 文献标识码：A 文章编号：1001—0017(2012)03—0018-05 of and of Films Acid onthe Its Synthesis3,5-Bis(4-aminophenoxy)BenzoicStudy PropertiesPolyimide u LIU En‘，YUYdn—hal‘，XUYo哨一fen‘and w∞-zhn矿 C池nRoe仇眦d (J．DeportmentofAppliedChemistry,DD哪∽Unlversity,‰l扣201620,China；2．ZhejimgCo．，眦，Ttdzlwu318050, China) Abstract：The 3．5一bis(4-aminophenoxy)benzoicacid(35RAPBA)issynthesized．Firstly,the 135BNPBA}ia condensationreactionof the synthesizedby 3,5-dihydroxy—benzoicacid(35DHBA)and hych．．)(1uinone(PCNB)；then 01135BAPBA of obtainedfunharreduction．Based films in acid(35BAPBA)isby monomer,avarietyaromatic叫yimidecontainingcarboxylgroups are 0f structuresynthesized，aadtheir雕—赢¨∞are．studied．Themeltingpointprepared3．5-bis(4-aminophenoxy)benzoic is kindsofthinfilmshave which have 245．8℃，All aw ultmvi,口let h袖purity hightransm／ssivityabove踟嘞theygood al∞orptionperformances；the water offdmsarelessthan isdeclaredthat haveexcellenl temile 0ffilms哦 abeorptiom 3％，wluch they hydrophobic雕娟m聃∞瞄；the