《5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes》.pdfVIP

CHEM. RES. CHINESE U. 2006 ，22 （4 ），419—422 5 ，10 ，15 ，20-Tetrakis（! -4-fluorobenzoyloxy ）phenyl Porphyrin and Its Transition Metal Complexes LIU Wei1 ＄，SHI Tong-shun2 and LIU Guo-fa2 1. College of Materials Science and Engineering ，Shandong Uniuersity of Technology ， Zibo 255049 ，P. R. China ；2. College of Chemistry ，Jilin Uniuersity ，Changchun 130023，P. R. China Received Sept. 5 ，2005 The properties of porphyrins can be changed through the choice of peripheraI substituents and inserted metaI ions. To obtain porphyrin compIexes with noveI structures，5 ，10，15，20-tetrakis （p -4-fIuorobenzoyIoxy ）phenyI por- phyrin（TFBOPPH ）and its transition metaI compIexes ｛TFBOPPM ［M = Mn （ ），Fe （ ），Co （ ），Ni （ ）， 2 ! ! 1 Cu（ ）and Zn（ ）］｝were synthesized and characterized by means of UV-Vis ，IR photoacoustic spectrometry ，H NMR ，eIementaI anaIyses ，moIar conductance ，and XPS methods. A structure is proposed ，in which one porphyrin moIecuIe is coordinated with a transition metaI ion in a tetradentate fashion ，whiIe the chIorine ion is the baIanceabIe anion in Fe（ ）and Mn（ ）compIexes. ! ! Keywords Porphyrin ；Synthesis ；Transition metaI ；CompIex Article ID 1005-9040 （2006 ） -04-419-04 Introduction Porphyrins are a cIass of organic moIecuIes with a macrocycIic tetrapyrroIe core and different subs