《Effects of Metal Oxide in ZSM-5 Zeolite on Its Catalytic Performance in FCC Process》.pdfVIP

China Petroleum Processing and Petrochemical Technology Catalyst research 2011,Vol. 13, No. 2, pp 43-46 June 30, 2011 Effects of Metal Oxide in ZSM-5 Zeolite on Its Catalytic Performance in FCC Process Qin Jinlai; Ouyang Ying; Li Minggang; Luo Yibin; Shu Xingtian (SINOPEC Research Institute of Petroleum Processing, Beijing 100083) Abstract: Effects of metal oxide in ZSM-5 zeolite on its catalytic performance in fluid catalytic cracking reaction were studied via characterization by XRD and FT-IR spectroscopy using pyridine and collidine as molecular probes, and the modified ZSM-5 zeolite was evaluated in a micro reactor using standard light diesel fraction as the feedstock. Test results indicate that the metal species introduced into the ZSM-5 zeolite had led to the formation of Lewis acid centers. When the modified ZSM-5 zeolite with the metal species on its surface was used as the catalyst in FCC reaction, both the propylene yield and the propylene concentration in the liquefied petroleum gas increased, but in the meantime, more hydrogen and coke were formed at high conversion rate under the joint action of nonselective cracking of Lewis acid centers and dehydro- genation at metal centers on its outside surface. Key words: ZSM-5 zeolite, metal oxide, fluid catalytic cracking, propylene 1 Introduction by impregnating the NH4+-exchanged ZSM-5 zeolite with 　 phosphoric acid and M salt (a soluble metal salt), fol- Propylene is an important starting material for mak- lowed by drying at 120 ℃ and calcination at 550 ℃. The ing chemical products. But there is a huge gap between