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《Synthesis and Crystal Structure of 2-(Diphenylphosphine oxide)-3-(diphenylphosphine oxide ethynyl) spiro[bicyclo[2.2.1]hepta-2,5-diene-7,1-cyclopropane]》.pdf
21 卷2 期 结 构 化 学 JIEGOU HUAXUE Vol. 21, No. 2
2002. 2 Chinese J. Struct. Chem. 149~152
Synthesis and Crystal Structure of 2-(Diphenylphosphine
oxide)-3-(diphenylphosphine oxide ethynyl) spiro
[bicyclo[2.2.1]hepta-2,5-diene-7,1´-cyclopropane]
HUANG Yao-Dong YU Hai-Tao MENG Ji-Ben WANG Yong- Mei
( Department of Chemistry, Nankai University, Tianjin 300071, China )
ABSTRACT The Diels-Alder reaction of bis(diphenylphosphine oxide)butadiyne (BDPPOB)
with spiro[2.4]hepta-4,6-diene affords the title compound, 2-(diphenylphosphine oxide)-3-(diphen-
ylphosphine oxide ethynyl)spiro[bicyclo[2.2.1] hepta-2,5-diene-7,1´-cyclopropane] (DDSHC,
C H O P , M = 542). Its crystal structure belongs to monoclinic system, space group P2 /n with
35 28 2 2 r 1
3
a =12.708(3), b = 14.666(4), c = 15.048(4) Å, â = 93.903(5) °, V = 2798.1(13) Å , Z = 4, Dc =
3 1
1.288g/cm , F (000)=1136, ì(MoKá) = 0.187mm , final R = 0.0626 and wR= 0.1422 for 4685
independent reflections with I 2ó(I). Structural analyses reveal that the title compound is
nonplanar and the dihedral angles between two phenyl rings around each phosphorus atom are
71.7(2) and 70.7(3)°, respectively.
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