过氧化氢与细胞色素c电化学传感器的研制与应用.pdfVIP

过氧化氢和细胞色素C电化学传感器的研制与应用 基于一种新颖的羧基化的核壳结构的Fe304@Au纳米粒子，制备了纳米修饰电极， 该电极可以实现CytC和GC电极之间的直接电子转移。进一步通过循环伏安扫描将Cyt C固定到该修饰电极表面，成功制备了Cyt CytC直接电子转移反应的同时，对过氧化氢电还原具有良好的电催化性能，可作为一 种新的过氧化氢电化学生物传感器进行更深入的开发和应用。 关键词：电化学传感器，杂多酸，聚￡．赖氨酸，多壁碳纳米管，细胞色素C，纳米粒子， 过氧化氢 II ABSTRACT ABSTRACT On thebasisof the andthe methodsofelectrochemical their introducingtype preparation sensors，and in seriesofthe applications ofelectrochemicalsensorsof c analyticalchemistry,a goodperformance Cyt and were a ofelectrodemodified and H202 preparedusingvariety materials many were researchworkswere describedas applicationsexploredrespectively．The briefly follows： I． Electrochemicalof and Properties Performanceof TungstogermanateElectrocatalytic ElectrodetotheReduction GeWllCo／P·oPD／GC ofH202 revealedCo-substitutedtrimeric Cyclicvoltammograms tungstogermanatecontainingKeggin onGCelectrodehadtwo of fragments reversibleredox inacid differencesof couples peaks aqueous．Their were31mVand peakpotential 35 to twotwo-electron my,respectively,whichcorrespondedrespectively reductions the four addition andthree accompanying addition,theelectrochemical by protons pr