ATO电极制备及其电催化降解苯酚的研究.pdf

摘 要 酚是一类用途非常广泛的化学品，特别是随着煤化工的迅速发展，含酚废水 的处理问题越来越严峻。而电催化氧化法被用于降解含酚废水，因其易于实现自 动化操作，良好的环境兼容性，较好的降解效果，而具有很好的发展前景。本文 在玻碳电极体系和 Ti 基电极体系中对于苯酚降解过程进行了详细研究。分别探 讨了电极制备方法以及降解操作条件等对苯酚降解的影响，并对苯酚的降解机理 进行分析。 首先，以玻碳电极作为阳极电催化苯酚氧化反应，使用循环伏安曲线研究支 持电解质酸碱性、扫描圈数、苯酚初始浓度、扫描速率及 ATO （氧化锡锑）粉 末负载量等因素对苯酚降解反应的影响，探究苯酚氧化反应过程，为含酚废水处 理提供电化学理论依据和指导。 其次，以 Ti 基电极作为阳极进行电催化苯酚降解实验，分别从电极制备方 法、降解操作条件、电极制备工艺参数方面对苯酚降解过程进行研究。结果表明， 晶种溶剂热生长-马弗炉焙烧法及滴涂-马弗炉焙烧法均能够制备导电性较好的 DSA 型电极。恒电压方式下，操作电压为 2 V 时，降解苯酚时，因其实现较短 的降解路径能达到较高的苯酚降解率 85%；恒电流方式下，电流密度参数为 10 mA·cm-2 时，因其较高的电流密度及电流效率，降解苯酚的效率较高。中性条件 下，因其溶液环境稳定，苯醌不易积累，苯酚实现较高的降解率。前驱液滴涂 1 次制备的电极效果较好，因其表面粗糙，活性高，且不易脱落。当涂层中 Sn: Sb 摩尔配比为 100:5 时，电极的导电性和催化活性最高。 最后，在实验基础上，对苯酚降解的反应路径进行了推断。 关键词：电催化；苯酚；Ti/Sb-SnO ；CV ；降解机理 2 ABSTRACT Phenol is a kind of chemical reagent with wide usage. Especially with the fast development of coal chemical engineering, the problem of phenol removing from waste water becomes more and more serious. And electro-catalysis is widely used to treat waste water with phenol, due to its simplicity for automatic operation, fine atmosphere compatibility and good degradation efficiency. In our research, we studied on phenol degradation respectively on GC substrate anode and Ti substrate anode. Anode preparation method and other parameters were respectively changed to study its effect on phenol oxidation, and further study the mechanism. First, glassy carbon was chosen as the electro-catalytic anode, CV curves were respectively recorded to study the effect of supporting electrolyte, scan circles, phenol original concentration, scan rate and ATO (Antimony doped Tin Oxide) coating on phenol degradation rate. The study can act as a theoretical basis