An investigation of the low-frequency torsional modes of trans-stilbene using Raman spectroscopy教材.pdfVIP
- 1、本文档共12页,可阅读全部内容。
- 2、原创力文档(book118)网站文档一经付费(服务费),不意味着购买了该文档的版权,仅供个人/单位学习、研究之用,不得用于商业用途,未经授权,严禁复制、发行、汇编、翻译或者网络传播等,侵权必究。
- 3、本站所有内容均由合作方或网友上传,本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺!文档内容仅供研究参考,付费前请自行鉴别。如您付费,意味着您自己接受本站规则且自行承担风险,本站不退款、不进行额外附加服务;查看《如何避免下载的几个坑》。如果您已付费下载过本站文档,您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等,请点击“版权申诉”(推荐),也可以打举报电话:400-050-0827(电话支持时间:9:00-18:30)。
- 5、该文档为VIP文档,如果想要下载,成为VIP会员后,下载免费。
- 6、成为VIP后,下载本文档将扣除1次下载权益。下载后,不支持退款、换文档。如有疑问请联系我们。
- 7、成为VIP后,您将拥有八大权益,权益包括:VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
- 8、VIP文档为合作方或网友上传,每下载1次, 网站将根据用户上传文档的质量评分、类型等,对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档
查看更多
Chemical Physics 51(1980) 77-88
0 North-Holland Publishing Company
AN INVESTIGATION OF THE LOW-FREQUENCY TORSIONAL MODES OF TRANS-STILBENE
USING RAMAN SPECTROSCOPY
A. BREE and M. EDELSON *
Chemisrry Department, Universiry of British Columbia, Vancouver. Brirish Columbia, Canada V6T 1 IV5
Received 13 February 1980
Evidence is presented which suggests that tmns-stilbene is nonplanar in fluid phases. The nearly planar molecule of the
solid distorts along the AU torsional coordinare in the melt and in solution, and distorts further in the vapour until the
angle between the phenyl and ethylene groups is about 30’. Approximate constants for the torsionaI coordinates have been
found up to u = 10 for the A, and u = 4 for the B, modes in the solid. The coordinates are quite anharmonic and strongly
coupkd.
1. Introduction In the past trans-stilbene has been assumed to be
planar in the ground electronic state [6,7 ] a!though
In this paper we attempt an analysis of the Raman calculations show that the potential energy surface is
spectrum of tralrs-stilbene, restricting our attention shallow with respect to torsions about the CC single
principally to the low-frequency modes. Raman spec- bonds adjacent to the central double bond [8,9] _
tra using mercury arc excitation have been reported However, an electron diffraction study [IO]
您可能关注的文档
- AD652 Voltage-to-Frequency Converter教材.pdf
- Adaptive strategies for high frequency trading教材.pdf
- Advances in High Frequency Strategies教材.pdf
- An equivalent-center method for quick frequency analysis of beams carrying a concentrated mass教材.pdf
- An Investigation of Incidental Vocabulary Acquisition in Relation to Learner Proficiency Level and Word Frequency教材.pdf
- Analysis of High Frequency Financial DataModels教材.pdf
- Application of frequency family separation教材.pdf
- Asymptotic high-frequency methods教材.pdf
- Availability_a Heuristic for Judging Frequency and Probability教材.pdf
- basic CMOS analog ic design Lecture 11 Frequency Response of Amplifiers教材.ppt
文档评论(0)