汇聚束电子衍射几何像分析在测量材料残余应变中的应用.pdfVIP

摘 要 复合材料在日常生活中具有相当的价值，本文通过 TEM 透射电镜，对颗粒增强 基复合材料 Al /Al O 进行 TEM 观察，对其界面处的残余应变进行了详细的研究，用 2 3 CBED 汇聚束电子衍射技术表征了 Al / Al2O3 界面处的 HOLZ 线的位移和偏转，通过 最小二乘法的计算拟合透射斑中心到 HOLZ 得出了延复合材料界面的应变大小的变 化，同时运用GPA 软件对喷射沉积 Al12Zn2.4Mg1.1Cu 合金的 GP 区进行几何像分析。 试验结果表明： 1、颗粒增强基复合材料 Al / Al O 的界面处的应变随着远离界面的距离增大而减 2 3 小随后又增大。出现了应变释放的现象。界面处的残余应变大小变化范围在 Al 的理 想点阵常数 0.405nm 之间，接近界面处的应变较大，说明界面处存在的较大的应变场， 残余应变值较大，但随着距离界面处的距离不断增大，应变值不断的缩小，说明远离 界面处的应变值减小，但是到达一定的距离时，应变有升高的趋势，这说明原来 TEM 区域的试样受到了压应变，到了一定的距离之后，压应变变成了拉应变，使得应变值 又升高。 2 、GPA 几何相分析的处理得到喷射沉积 Al12Zn2.4Mg1.1Cu 合金的 GP 区的残余 应变大小要小于周围原子场的应变，说明 GP 区的的原子排列较好，位错较少，应变 场较小。而且 GP 区的原子和周围原子的结合存在错排，使得周围原子的位错应变升 高。 关键词：复合材料；残余应变；CBED ；GPA Abstract The particle reinforced composites and the high strength Al alloys prepared by spray forming process have shared a brilliant position in our country’s development. This paper, through the TEM, made several observation about the particle reinforced Al / Al O composites, observed the appearance of the reinforced particle, elaborated 2 3 the tilting and moving of the HOLZ line between the interface. The transformation of the strain was calculated through the least square method using the distance from the transmission center to the HOLZ line. The GPA software analyzed the GP area in the Al12Zn2.4Mg1.1Cu alloy. The result shows that: 1. The strain existing between the interfaces of the composites turned down at first and then turned large, which is concluded as the strain releasing. The residual strain’s transformation was among the range of the ideal lattice parameter 0.405nm, the high strain existing closed to the interface demonstrated the high residual strain field. However, the strain turned down afterward with the distance versus the interface increased. That is to say, the strain bec