Multi-component Hydrogen-bonding Organic Salts Formed from 1-Methylpiperazine with Aromatic Carboxylic Acids： Synthons Cooperation and Crystal Structures.pdfVIP

Chem．Res．Chin．Univ．，2015，31(1)，9一l5 doi：10．1007／s40242．0l5．4304．2 M ulti-·componentHydrogen——bondingOrganicSaltsFormedfrom 1-M ethylpiperazinewithAromaticCarboxylicAcids： SynthonsCooperationandCrystalStructures YANGYu XuWenyan。HUYaniing，Ⅵ NGLei andHUANGKeke ． KeyLaboratoryofEco—chemicalEngineering,Ministry ofEducation，LaboratoryofInorganicSynthesisand AppliedChemistry,CollegeofChemistryandMolecularEngineering, QingdaoUniversityofScienceandTechnology,Qingdao266042，PR．China； 2．StateKeyLaboratoryofInorganicSynthesisandPreparativeChemistry,JilinUniversiyt, Changchun130012，P R．China Abstract 1-M ethylpiperazinewasemployedtocrystallizewith2，4-dihydrOxybenzoicacidand1，8-naphthaleneacid， affording two multi—component hydrogen—bonding salts 【(CsHI4N2)。(C7H504)2一H‘20】(1) and 【(CsH14N2) (C12H604)2-．2H20](2)．ThesetwoformsofsaltsarebothmonoclinicsystemswithspacegroupP21／c(14)． Thelatticeparametersofsalts1and2raea1．32666(10)nm，b=0．90527(7)nm，c=1．67107(13)nm， 103．125(1)。 nada 1．4950(2)nm，b=O．75242(15)nm，c 1．6563(3)am， 92．834(2)。，respectively．Expectedclassicalhydrogen bondsN— H…O na dO— H…O aDpera inhtechargetransfersalts．na dasymmetricunitsofthesetwoformsbothcon． tainwatermoleculeswhich playa significantrolein building novelsupramoleculararchitectures．Robusthydro． gen-bondinteractionsbewt eenl-methylpiperazinena daromaticacidprovidesuffi cientdrivingforcetodirectthetwo crystalstothree-dimensionalstructures．WeakinteractionsC…H ·O emerginginsalts1na d2furtherenhancetheir crystalstructures．Asaconsequence．hydrogen-bonding interactions in these compoundsarford diverse 3D net suprma olecular architectures．Thermal stability of these