2012(chempluschem)混合超级电容器.pdfVIP

DOI: 10.1002/cplu.201200023 Fabrication of High Energy-Density Hybrid Supercapacitors Using Electrospun V2O5 Nanofibers with a Self-Supported Carbon Nanotube Network Vanchiappan Aravindan,[a] Yan Ling Cheah,[b] Wai Fatt Mak,[b] Grace Wee,[b] Bobba V. R. Chowdari,*[c] and Srinivasan Madhavi*[a, b] A simple electrospinning technique is employed for the prepa- nanofibers are used to fabricate a hybrid electrochemical ca- ration of high-performance V2O5 nanofibers. The fibers thus pacitor (HEC) and it is coupled with a substrate-free single- prepared are subjected to heat treatment under the optimized walled carbon nanotube (SWCNT) network (called “Bucky conditions at 400 8C in air to achieve a single phase. The paper”) in a conventional organic electrolyte solution. Superca- powder X-ray diffraction pattern confirms the formation of an pacitive behavior of HEC is studied in both potentiostatic and orthorhombic structure with Pmmn space group. Morphologi- galvanostatic modes at room temperature. The HEC demon- cal studies conducted by means of scanning electron micros- strated very stable and excellent cycling behavior during copy (SEM) and transmission electron microscopy (TEM), clearly 3500 cycles of galvanostatic charge and discharge tests. This reveal the presence of a highly interconnected network of hybrid system is also well established during the rate capability fibers with the diameter ranging from approximately 500– studies from the applied current density of 30 to 210 mA g1 800 nm. After the heat treatment, translation of smooth fibrous and