am_2012_红外光谱探测碳酸钙的微观结构.pdf

www.advmat.de www.MaterialsV N Decoupling Local Disorder and Optical Effects in Infrared O I T Spectra: Differentiating Between Calcites with Different A C I Origins N U M Kristin M. Poduska,* Lior Regev, Elisabetta Boaretto, Lia Addadi, Steve Weiner, M O Leeor Kronik, and Stefano Curtarolo* C Perfect crystallinity is defi ned as three-dimensional, atomic- vary slightly depending on the specimen size, shape, and the level periodic order in a material.[1] The degree of crystallinity polarization of the incident light.[4] Thus, the phonon mode can be strongly affected by the specimen’s formation process may be manifested as a broad and complex IR absorption peak and often plays an important role in its resulting chemical due to phonon-optical coupling (polariton) contributions from and mechanical properties. Calcium carbonate (CaCO3 ), for bulk, surface, transverse and longitudinal optical modes. Theo- example, exhibits a wide range of gradually changing crystal- retical studies show that peak shapes become much simpler, linity. The two extremes of this range are single-crystalline cal- supporting only a single optical surface (Frölich) mode, once cite, which exhibits a single periodic order across macroscopic the size of a specimen’s particles are too small to support wave- distances, and amorphous calcium carbonate (ACC),[2] which like (bulk) polariton modes.[5] Nevertheless, prediction of peak exhibits a degree of short-range