模拟光合作用Z型反应光催化分解水的初步地研究.pdfVIP

模拟光合作用Z 型反应光催化分解水的初步研究 以I / IO − 为中间体的光解水体系的产氢产氧性能，以及探讨了在真空 3 反应系统和排空反应系统中以 K Ce Ta O 和 WO 为催化剂，以 4 2 10 30 3 Fe2+/Fe3+为中间体的光解水体系的产氢、产氧性能。结果表明，以上 三种光解水体系中并不能确定Z 型反应是否实现，但在研究中发现， 光催化剂的活性与反应器中压力有关，在真空条件下光催化剂的活性 明显高于排空条件下光催化剂的活性。 综上所述，在本论文中实现了Z 型反应光催化分解水同时产氢、 产氧。在研究中得出的一些结论对下一步的工作有很好的借鉴意义。 关键词：氢能， Z 型反应，光解水，光催化剂，氧化还原中间体 5 模拟光合作用Z 型反应光催化分解水的初步研究 A PHOTOCATALYTIC SYSTEM SPLITTING WATER INTO H AND O MIMICKING Z-SCHEME 2 2 MECHANISM ABSTRACT Hydrogen energy is well recognized as one of the most ideal energy to solve the energy and environmental problems confronting the whole society currently, and the development of hydrogen energy has been attracted more attention. Among these ways and methods deployed to develop hydrogen, splitting water to H2 using semiconductor photocatalysts is one of the most promising and ideal way considering energy cost, resource and environmental issues. It is possible to employ visible light by photocatalytic water splitting system mimicking Z-scheme mechanism. This dissertation began with the introduction of the ways of photocatalytic water splitting, and explained the mechanism of the watersplitting, typical photocatalysts, and the factors which relate to the activity of the photocatalyst. Subsequently the mechanism of Z-scheme water splitting was clarified. 6 模拟光合作用Z 型反应光催化分解水的初步研究 The dissertation discussed the influence o