共价键链杯芳烃-四硫富瓦烯超分子体系研究进展有机化学.pdfVIP

DOI: 10.6023/cjoc201404022 综述与进展 有机化学 Chinese Journal of Organic Chemistry REVIEW 共价键链杯芳烃-四硫富瓦烯超分子体系研究进展 赵邦屯*,a 朱卫民*,b (a 洛阳师范学院化学化工学院 洛阳 471022) (b 郑州大学化学与分子工程学院 郑州 450010) 摘要 综述了共价键链的杯芳烃-四硫富瓦烯超分子主体化合物的设计合成及其在电化学调控的分子识别、离子调节 的电子转移行为和分子组装等领域的研究进展. 关键词 杯芳烃; 四硫富瓦烯; 分子识别; 电子转移; 分子组装 Progress on Covalently Bonded Calixarene-Tetrathiafulvalene Supramolecules Zhao, Bangtun*,a Zhu, Weimin*,b (a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022) (b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001) Abstract The main focus of this review is on the supramolecular calixarene-tetrathiafulvalene chemistry. The general as- pects of molecular design of calixarene-tetrathiafulvalene systems are reviewed on the attachment of tetrathiafulvalene unit(s) on the calixarene framework through the upper rims or lower rims, and the structually related thiacalixarene and calixpyrroles and so on. This survey is also presented from the view of supamolecular application of calixarene-tetrathiafulvalene systems in electrochemically molecular recognition, ion-mediated electron transfer, molecular assembly, molecular switches and devices etc. Keywords calixarene; tetrathiafulvalene; molecular recognition; electron transfer; molecular assembly 超分子电化学(Suparmolecular Electrochemistry)是 的研究兴趣[5](Scheme 1). 四硫富瓦烯(Tetrathiafulva- 超分子化学与电化学相互融合的前沿领域[1]. 超分子电 lene, 简称 TTF)是一种稳定、可逆的两电子给体, 在