双臂型方酰胺多齿配体的合成有机化学.pdfVIP

者就化学 YOU.rt HUAXUE , 1991 , 11 , 382-387 研究论文 双臂型方瞰服多齿配体的合成 在雄其飞肖 森、陈益告IJ 、罗吴明 (四川大学化学系，四川，成郁， 610064) Synthesis of Novel MuItidentate Ligands with Two Arms Derived .‘ from Squaric Acid YUAN De-Qi飞 XIAO Sen , CHEN Yi-Zhao , LUO Mei-Ming (Ðtpartment 01 Chemistry, Sichuan University, 610064 Chengdu , Sichuan) Abstr町t. E地ht new multidentate ligands (5 a--5 f , 5 i , 5 j) have been synthesized by fe- • ~ f1uxing squaric acid with amines 4 which were obtained from chlorièes 2 or alcohols 1 through nitr。一compounds 3 (3 f , 3 g and .. f have not been hitherto reported). These chromo- genic ligands showing maximum absorption around 410 nm with 19 e ~ 4 .4 contain a dioxocyclo- butene skeleton and two arms of oligoethyIene glycol ethers which a Ilow the negatively charg- ed oxygen atoms on the four- membercd ring to serve as central coordinating atoms. Very interestingly. 5 c turned out to be a good active constituent for NH -selective electrode. in 3 2 addition to its coordinations to UO; + and zr0 +. This phenomenon is suppo~ed to originate from the interaction between the small and high1y positively charged squaric ring and ligand NH3 bearing a pair of unshared electrons. D幅criptof. multidentate ligands. squaric acid derivertives. squaraines. synthesis 自 1959 年发现方酸以来[l] ，已有许多文献 醋链等，就能获得一类新的多齿配体。可以预 报道其可以与多种金属肖子，尤其是过渡企属 料，这类配体将表现出特殊的化学行为。有鉴 离子形成配合物I 町，但方眈胶多齿自己体的研究 于此，我们合成并研究了一系列新型