双-(O,O-二正丁基二硫代磷酸酯)合镍-二吡啶加合物的晶体结构和分子结构有机化学.pdfVIP

第 5 期 双-(ο ， 0-二正丁主二肮代磷酸脂)合何-二日比院加合物的晶体结构和分子结构 369 36.113. Chem. , 1985 , 28 , 399; b. li东庆4、朽震亨、 [6] Gutmann , V. , The Donor-Acceptor App胃 装再明，科学通报， 1987, 1 时. 593 0 roach to Molecular lnteraction Chapter 2, [ 8 ] a. du pont. Rritish Patent 583 , 264 (946); p. ,!1. Plenum Press , New York. 1978. b. Rigby , G. W.; Schmeder , H. E. , U. S. [7] a. Chen., Q. Y.; Yang; Z. Y. , J. b1 uorine. P. 2 ,409 ,315 (1 946). 来 9悟 唱t * 来 来 有机化节(YOUJI HUAXU酌. 1987(5) , 396~373(研究简报) 双一(0， 0 …二正丁基二硫代磷酸醋)合镇一二毗瞧加合物的晶体结 构和分子结构 立IJ ilt-t(;-_ * ，林埠昌， (福州大学、结构化学研究室，福州、[) 1全 正，俞运鸭 游效曾. (南京大学配位化学研究所，南京) The Crystal and Molecular Structure of the Adduct of Bis (0 ,OJ - Dibutyldithiophosphato) Nickel (11) with Pyridine LlU Shi-Xiong LlN Chi-Chang (lnstitute of Structural Chemistry, Fuzhou University, Fuznou) XU Zheng YU Yun-Peng YOU Xiao-Zeng (C∞rdination Chemistry lnstitute. Nan;ing University. Nanjing) Abstract: The crystal and molecular structul S ot the title compound have been determined by X-ray diffraction method. The crystal belongs to a monoclinic system with Q=c 13.753(3). b= 9.256(2). c== 15.306(3)λ ，自 =113.80 (1)飞 v = 1783λ3; space group qh- P21/C; Z == 2. D.. = 1.300 g.cm寸. M = 697.37. F(OOO) = 736 e. The structure was solved by heavy atom method and refined by least square technique to finaJ discre归ncy factor of R = 0.062. Ni (11) is he- xacoordinated and lies on the plane formed by four sulfur atoms. Two py