有机二阶非线性光学发色团的研究进展有机化学.pdfVIP

2011 年第 31 卷 有 机 化 学 Vol. 31, 2011 第 9 期, 1337～1349 Chinese Journal of Organic Chemistry No. 9, 1337～1349 ·综述与进展· 有机二阶非线性光学发色团的研究进展 李倩倩 秦金贵 李 振* (武汉大学化学与分子科学学院 湖北省有机高分子光电功能材料重点实验室 武汉 430072) 摘要 近年来, 科学家们通过引进杂环片段、采用双(或多)官能化以及运用分子间弱相互作用等方法, 在二阶非线性光 学发色团的性能优化方面取得了较大进展. 结合本课题组的研究, 对此领域的研究进行了较全面的综述, 并特别针对 “非线性-透光性”矛盾的解决途径进行了较为详细的介绍. 关键词 二阶非线性光学效应; 有机发色团; 分子一阶超极化率; 透明性 Recent Progress of Organic Second-Order Nonlinear Optical Chromophores Li, Qianqian Qin, Jingui Li, Zhen* (Hubei Key Laboratory on Organic and Polymeric Opto-Electronic Materials, Department of Chemistry, Wuhan University, Wuhan 430072) Abstract Second-order nonlinear optical (NLO) materials have played a very important role in laser tech- nology since the invention of laser. As to the organic NLO materials, the chromophores are the key compo- nent. To tune the nonlinearity-transparency trade-off in organic NLO chromophores, several promising strategies were attempted, including the introduction of heterocyclic rings, dual (mutiple) functionalizations and utilization of the interactions between chromophore moieties. In this article, recent progress in this field is reviewed. Keywords second-order nonlinear optical effect; chromophore; molecular first-order hyperpolarizability; transparency (2) (3) 非线性光学是研究光与物质相互作用的一门学科, χ , γ 和χ 分别是微观和宏观的线性、二次非线性和三 非线性光学