新的芳酰肼分子钳人工受体的微波干法合成及其识别性能研究有机化学.pdfVIP

2010 年第 30 卷 有 机 化 学 Vol. 30, 2010 第 8 期, 1220～1225 Chinese Journal of Organic Chemistry No. 8, 1220～1225 ·研究论文· 新的芳酰肼分子钳人工受体的微波干法合成及其识别性能研究 石培育 赵志刚* 李晓蕊 刘兴利 (西南民族大学化学与环境保护学院 成都 610041) 摘要 在微波辐射无溶剂条件下, 以间苯二酚为起始原料, 固体 K2CO3 为载体, 设计合成了 9 个新的芳杂环酰肼分子 钳人工受体. 其结构均经 1H NMR, IR, MS 及元素分析确证. 同传统的方法相比, 该法具有简单、快速、高效和对环境 友好等优点. 利用紫外可见分光光度滴定法初步考察了这类分子钳对卤素阴离子的识别性能. 结果表明, 该类分子钳 对 I－具有良好的选择性识别性能. 关键词 酰肼; 分子钳; 微波辐射; 分子识别 Studies on the Synthesis of Novel Arylhydrazide Type Molecular Tweezer Artificial Receptors in Solvent-Free Conditions under Microwave Irradiation and Its Recognition Properties Shi, Peiyu Zhao, Zhigang* Li, Xiaorui Liu, Xingli (College of Chemistry and Environmental Protection Engineering, Southwest University for Nationalities, Chengdu 610041) Abstract Nine new arylhydrazide type molecular tweezer artificial receptors have been designed and syn- thesized with high yields using solid K CO as supporter in solvent-free conditions under microwave irradia- 2 3 1 tion. The structures of all molecular tweezers were characterized by H NMR, IR, MS techniques and ele- mental analysis. Compared with the conventional heating method, this method is simple, fast, efficient and eco-friendly. The recognition properties for halogen anions were investigated by UV-vis spectra titration. The preliminary results indicate that these molecular tweezers show selective recognition for iodine anions. Keywords