新型罗丹明B类荧光探针的合成及其对Fe3+识别研究有机化学.pdfVIP

DOI: 10.6023/cjoc201307039 研究论文 有机化学 Chinese Journal of Organic Chemistry ARTICLE 新型罗丹明B 类荧光探针的合成及其对Fe3＋识别研究 孟文斐 杨美盼 成 昭 李少妮 杨秉勤* (西北大学化学与材料科学学院 合成与天然功能分子化学教育部重点实验室 西安 710069) 摘要 以罗丹明B 和间氨基吡啶缩合反应得到新型罗丹明 B 衍生物 L1, 并用 1H NMR, IR, HRMS-ESI 及X 射线对其结 构进行了确证. 通过荧光光谱法研究了目标物 L1 在水溶液中与金属离子的识别特性. 结果表明目标物 L1 作为荧光探 针可选择性的比色识别 Fe3＋, 并且受常见离子的干扰较小. 探针 L1 的荧光强度与 Fe3＋浓度(1 ×10－6～9 ×10－6 mol/L) 呈较好的线性关系. 关键词 荧光探针; 罗丹明; 铁离子; 识别; 荧光响应 Synthesis of Novel Rhodamine B Fluorescent Probe and Recognition Study to Fe3＋ Meng, Wenfei Yang, Meipan Cheng, Zhao Li, Shaoni Yang, Bingqin* (Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry, Northwest University, Xian 710069) Abstract A novel rhodamine B derivative L1 was synthesized facilely by the condensation reaction of rhodamine B hy- drazide and 3-aminopyridine, and its structure was characterized by 1H NMR, IR, HRMS-ESI and X-ray techniques. The rec- ognition properties of the target compound L1 with metal ions had been investigated in water solution by the fluorescence spectrophotometry. The results showed that the probe L1 exhibited the selective colorimetric recognition to Fe3＋than other metal ions. When the concentration of Fe3＋ was in the range of 1 ×10－6～9 ×10－6 mol/L, there was a good linearity between the fluorescence intensity of the probe L1 and the concentration of Fe3＋. Keywords fluorescent probe; rhodamine; iron ion; recognition; fluorescence r