原创力文档New Catalytic Proportions for Syntheses of SWNT Bundles （Ropes） and Its Characterization.pdfVIP
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New Catalytic Proportions for Syntheses of SWNT Bundles （Ropes） and Its Characterization.pdf
维普资讯
New CatalyticProportionsforSynthesesof
SWNTBundles(Ropes)andItsCharacterization
DAITong，DAIJian-feng
(SchoolofSciences，LanzhouUniversityofTechnology，Lanzhou730050，CHN)
AhItrIct：Thesingle-walledcarbonnanotube(SW NT)bundlesandropeshavebeenpreparedbyusingthe
anodearcdischargeplasmatoevaporatethegraphiterodswhichcontainFe，CoandNipowdersascatalystin
Heatmosphere．Manypurifyingmethodsareusedfortheproducts．ItindicatesthatthesynthesisofSW NTs
hasbeengreatlyaffectedbythepreparationparametersofcatalyzer，thebuffergasanditspressure，thearc
currentintensity，etc．Theoptimalcondition forpreparingSW NTsin ourcasehasbeen proposed．The
formingmechanism ofthe SW NTsbundlesand ropes isalso studied qualitatively．Theevaporated single
graphitesheettendstoreduceitsactiveenergy． ．
Keywords：Single-walledcarbonnanotubes；Catalyzer；Evaporation；Thermogravimetry
cLcnumber：TQ314．24 2 Docm ntcode：A AttickID：1007—0206(2006)03—0168一O5
1 Introduction
Numerousrecentresearcheshaveprovedthatcarbonnanotubesexhibitmarvellousmaterialproperties
duetotheiruniquestructures．Thealignedtrim cutSWNT bundleshavetheexcellentcombinationof
propertiessuch asnanometer size in diameter，structuralintegrity， high electricalconductivity and
chemicalstabilitythatmakeitgoodelectronemitters．Suchdeviceshaveshownsuperiorqualitiesincluding
low turn—onelectricfield，highemissioncurrentdensityandhighstability．Ontheotherhand，duetothe
VanderW aalsbindingbetweensingle-walledcarbonnanotubes(SW NTs)，oncetheropesareformed，the
homogeneousdispersion into the composites become a problem thatneedsfurther improvementand
optimization．
Growingnanotubesbyplasmaanodearcdis
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