基于分形理论的水汽在燃煤细颗粒表面异质核化数值研究.pdfVIP

第 29 卷 第 11 期 中 国 电 机 工 程 学 报 Vol.29 No.11 Apr. 15, 2009 50 2009 年 4 月 15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 0258-8013 (2009) 11-0050-07 X 51 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 基于分形理论的水汽在燃煤细颗粒表面 异质核化数值研究 颜金培，杨林军，凡凤仙，沈湘林 ( 东南大学能源与环境学院，江苏省 南京市 210096) Numerical Analysis of Water Vapor Nucleation on Fine Particles From Coal Combustion Based on Fractal Model YAN Jin-pei, YANG Lin-jun, FAN Feng-xian, SHEN Xiang-lin (School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Province, China) ABSTRACT: A numerical prediction of water vapor 颗粒的不规则结构能使液滴胚胎形成临界吉布斯自由能降 heterogeneous nucleation behavior on fine particles from coal 低、成核速率增大、核化所需的临界过饱和度降低，可提高 combustion was carried out according to Fletcher’s theory 过饱和水汽在其表面的成核能力；此外，核化所需临界过饱 under the condition with and without considering the fractal 和度随颗粒粒径增大而降低，特别是小于 0.1 μm 的颗粒，粒 characteristics of the fine particle. Microstructures of fine 径对过饱和度的影响更为显著，随温度提高核化所需的临界 particles in different sizes were analyzed by scanning electron 过饱和度相应降低。 microscopy (SEM). Microstructures of fine particles were 关键词：燃煤细颗粒；异质核化；过饱和；吉布斯自由能 investigated using fractal model. The results show that it has a classical fractal structure of fine particles from coal combustion, 0 引言 with dimension between 2.21 and 2.63. The heterophilic properties of fine particles can reduce the Gibbs free energy of 可吸入颗粒物易于富集有毒的重金属、有机污 embryo formation and cause the magnitude of nucleati