基于平行反应模型的稻壳生物油燃烧机制研究.pdfVIP

第 29 卷 第 29 期 中 国 电 机 工 程 学 报 Vol.29 No.29 Oct. 15, 2009 2009 年 10 月 15 日 Proceedings of the CSEE ©2009 Chin.Soc.for Elec.Eng. 89 文章编号：0258-8013 (2009) 29-0089-07 中图分类号：TK 6 文献标志码：A 学科分类号：470·20 基于平行反应模型的稻壳生物油燃烧机制研究 李睿，金保升，仲兆平，傅旭峰，贾相如 ( 东南大学能源与环境学院，江苏省 南京市 210096) Mechanism Research on Rice Husk Bio-oil Combustion Based on Parallel Reaction Model LI Rui, JIN Bao-sheng, ZHONG Zhao-ping, FU Xu-feng, JIA Xiang-ru (School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Province, China) ABSTRACT: The combustion of bio-oil from rice husk was 合峰对应轻质有机物的挥发，第 4 个拟合峰对应重质有机物 carried out on a thermogravimetric (TG) analyzer coupled with 的分解和缓慢氧化，最后2 个拟合峰对应二次焦炭的燃烧。 a Fourier transform infrared spectroscopy (FTIR). Based on 升温速率的提高影响各拟合峰所占份额，加剧生物油挥发， parallel reaction model, multi-peaks Gaussian fitting was 减少二次焦炭生成，但仅对最后 2 个拟合峰的动力学参数有 utilized to analyze the first derivative curves of weight loss at 明显影响。最后结合多峰高斯拟合结果和红外分析结果提出 different heating rates and the evolution of gas released from 稻壳生物油燃烧模型。 combustion was investigated by FTIR. The results show that 关键词：稻壳生物油；平行反应模型；多峰高斯拟合；热重– the first derivative curves of weight loss could be described as 红外联用技术；燃烧 an overlap of six Gauss peaks. The first three peaks are attributed to the volatilization of light compounds, the forth 0 引言 peak is corresponding to the heavy compounds decomposition, 生物质具有可再生与低污染的特点，其有效利 and the last two peaks are characteristic