CaCO3对煤灰熔融特性和黏温特性影响的研究.pdfVIP

第32 卷 第20 期 中 国 电 机 工 程 学 报 Vol.32 No.20 Jul.15, 2012 2012 年7 月15 日 Proceedings of the CSEE ©2012 Chin.Soc.for Elec.Eng. 49 文章编号：0258-8013 (2012) 20-0049-07 中图分类号：TQ 546 文献标志码：A 学科分类号：470·10 CaCO 对煤灰熔融特性和黏温特性影响的研究 3 袁海平，梁钦锋，刘海峰，龚欣 (华东理工大学煤气化教育部重点实验室，上海市 徐汇区 200237) Effects of CaCO on the Fusion Characteristic and Viscosity-temperature 3 Behaviour of Coal Ashes YUAN Haiping, LIANG Qinfeng, LIU Haifeng, GONG Xin (Key Laboratory of Coal Gasification of Ministry of Education, East China University of Science and Technology, Xuhui District, Shanghai 200237, China) ABSTRACT: In this paper, the effect of CaCO on the fusion 并采用热力学计算软件FactSage 6.1 中的Phase Diagram 和 3 characteristic and viscosity-temperature behavior of coal ashes Equilib 模块进行热力学平衡计算。结果表明，Al O 和SiO 2 3 2 was studied. Three coal samples applied in entrained flow 含量较高的煤灰样品在熔融的过程中产生大量的莫来石，导 gasification plant in China, including coal A, B, and C were 致其灰熔点较高。CaCO3 的添加可以有效抑制莫来石的生 prepared as raw materials for the ash fusion temperature 成，改变高温下煤灰中主固相物质的类型，降低固相物质的 (AFT) and viscosity tests. The thermodynamic equilibrium 百分含量，降低煤灰的全液相温度，从而达到降低煤灰熔融 modeling was carried out using Phase Diagram and Equilib 性温度和黏度以及改变渣型的效果。数值计算的结果与试验 modules of FactSage 6.1 software. The results indicate that a 结果基本一致，表明化学热力学反