NO在活性炭表面的吸附平衡和动力学研究.pdfVIP

第 30 卷 第 35 期 中 国 电 机 工 程 学 报 Vol.30 No.35 Dec.15, 2010 2010 年 12 月 15 日 Proceedings of the CSEE ©2010 Chin.Soc.for Elec.Eng. 49 文章编号：0258-8013 (2010) 35-0049-06 中图分类号：TQ 53 文献标志码：A 学科分类号：470·10 NO 在活性炭表面的吸附平衡和动力学研究 尹艳山，张军，盛昌栋 ( 东南大学能源与环境学院，江苏省 南京市 210096) Adsorption Equilibrium and Kinetics of NO Removal on Activated Carbons YIN Yanshan, ZHANG Jun, SHENG Changdong (School of Energy and Environment, Southeast University, Nanjing 210096, Jiangsu Province, China) ABSTRACT: The adsorption equilibrium and kinetics of NO 分别拟合吸附数据，发现 Langmuir 方程能够很好地预测 removal on activated carbons (ACs) were investigated based on NO 在活性炭表面的吸附平衡。使用颗粒内扩散方程、 a quartz fixed bed reactor by temperature programmed reaction Langmuir 速率方程和 Elovich 方程分别拟合动力学数据，结 (TPR) and isothermal reaction. The results of TPR were in 果表明低温时活性炭-NO 的动力学符合Elovich 方程，其机 good agreement with that of isothermal reaction. ACs-NO in 制由化学吸附控制，起始吸附速率随着温度升高而降低，吸 TPR (30~600 ℃ ) showed three temperature regions, 附活化能随着吸附量增加而线性增大。高温时等温实验结果 corresponding to chemisorption, transition and reduction 表明，活性炭-NO 由还原反应机制控制。 reaction respectively with increasing temperature. Compared 关键词：活性炭；NO 吸附；吸附平衡；动力学 with Freundlich and Temkin isotherm equation, Langmuir isotherm equation presented better fitted results for NO 0 引言 adsorption equilibrium. Three kinetic models including intra-particle diffusion equation, Langmuir rate equation and NO 是燃煤产生的主要大气污染物之一，排放 Elovich equation were applied in describing the reaction of 在大气中的 NO 经过一系列化学作用