O2_CO2气氛下无烟煤及烟煤燃烧NO释放特性对比试验研究.pdfVIP

第31 卷 第35 期 中 国 电 机 工 程 学 报 Vol.31 No.35 Dec.15, 2011 2011 年12 月15 日 Proceedings of the CSEE ©2011 Chin.Soc.for Elec.Eng. 53 0258-8013 (2011) 35-0053-06 TK 16 A 470 10 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ O /CO 气氛下无烟煤 2 2 及烟煤燃烧NO 释放特性对比试验研究 游卓，王智化，周志军，刘建忠，周俊虎，岑可法 (能源清洁利用国家重点实验室(浙江大学) ，浙江省 杭州市 310027) NO Emission During Combustion of Anthracite and Bituminous Coal in O /CO Atmosphere 2 2 YOU Zhuo, WANG Zhihua, ZHOU Zhijun, LIU Jianzhong, ZHOU Junhu, CEN Kefa (State Key Laboratory of Clean Energy Utilization (Zhejiang University), Hangzhou, 310027, Zhejiang Province, China) ABSTRACT: NO emission of bituminous coal and anthracite 气量，提高燃烧效率并缩小设备体积；3 ）降低NOx during combustion in O2/CO2 atmosphere were studied at [1-4] 排放 。 1073 K and 21%~100% oxygen in a horizontal tube oven. The 在煤燃烧过程中，挥发分析出阶段燃料N 以主 results show that NO formed in O /CO atmosphere is less than 2 2 要由NH3 和HCN 组成的气相前驱物经过一系列复 half of that in air. It is believed that CO formed through 杂的气相化学反应的方式生成NOx [1] 。这些前驱物 heterogeneous reaction is the main factor for the NO reduction. 具有还原性，可将NO 还原为N2 。煤在富氧燃烧时 NO increases with oxygen concentration until levels out. The emission process of NO is affected by fuel types. A lot of NO 再循环烟气使一部分已经生成的 NOx 在燃烧器附 will be formed accompanied with the massive CO emission 近还原，燃