a promoting effect of dilution of pd sites due to gold surface segregation under reaction conditions on supported pd–au catalysts for the selective hydrogenation of 1,5-cyclooctadiene：一种促进pd网站由于黄金表面偏析反应条件对负载型钯–金催化剂1,5-环辛二烯选择性加氢的稀释效应.pdfVIP

Catalysis Today 259 (2015) 213–221 Contents lists available at ScienceDirect Catalysis Today j o u r n a l h o me p a ge : w w w. elsev /locate/cattod A promoting effect of dilution of Pd sites due to gold surface segregation under reaction conditions on supported Pd–Au catalysts for the selective hydrogenation of 1,5-cyclooctadiene Patricia Concepción a,∗ , Saray García a , Juan Carlos Hernández-Garrido b , Jose Juan Calvino b , Avelino Corma a,c,∗∗ a Instituto de Tecnología Química CSIC-UPV, Universidad Politécnica de Valencia, 46022 Valencia, Spain b Departamento de Ciencia de los Materiales, Ingeniería Metalúrgica y Química Inorgánica, Universidad de Cádiz, Facultad de Ciencias, Campus Río San Pedro, Puerto Real, 11510 Cádiz, Spain c King Fahd University of Petroleum and Minerals, P. O. Box 989, Dhahran 31261, Saudi Arabia a r t i c l e i n f o a b s t r a c t Article history: Restructuration of AuPd/CeO2 catalysts is observed during 1,5-cyclooctadiene hydrogenation, with gold Received 30 March 2015 surface segregation in which gold acts as a diluent of Pd surface sites. The composition of the catalyst Received in revised form 14 July 2015 influences the catalytic behavior, and an optimum is observed at a Pd/Au molar ratio of 0.13, as deter- Accepted 16 July 2015 mined by X-EDS STEM. Pd–Au/CeO2 shows higher hydrogenation rates (11.2 × 10−5 mol/g s) versus the Available online 11 August 2015 −5 −5