洗选对煤结构及热解特性的影响.pdfVIP

第 33 卷 第 23 期 中 国 电 机 工 程 学 报 Vol.33 No.23 Aug.15, 2013 68 2013 年 8 月 15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 0258-8013 (2013) 23-0068-07 TQ 530 TK 16 A 470 20 文章编号： 中图分类号： ； 文献标志码： 学科分类号： ⋅ 洗选对煤结构及其热解特性的影响 惠贺龙，付兴民，王小华，韦云钊，贾晋炜，舒新前 ( 中国矿业大学(北京)化学与环境工程学院，北京市 海淀区 100083) Effect of Washing Process on the Structure and Pyrolysis Characteristics of Coal HUI Helong, FU Xingmin, WANG Xiaohua, WEI Yunzhao, JIA Jinwei, SHU Xinqian (Chemical and Environmental Engineering, China University of Mining Technology (Beijing), Haidian District, Beijing 100083, China) ABSTRACT: The samples of raw coal (RC), clean coal (CC), 富氢基团(CH 、CH ) 的脱落，但对脂链结构没有影响。在 3 2 tailings (TC) and demineralized coal (DC) used in this study 煤的热解过程中，灰分的存在降低了煤炭的热解缩聚程度， were provided by Hexi Coal. The effects of coal preparation on 增加了热解活化能，造成热解特征温度均向高温区推移；并 the coal structure and pyrolysis characteristics were 阻碍了煤焦基本晶格单元纵向的热缩聚，抑制了煤焦的石墨 investigated by XRD, FT-IR and TG/DTG, and the crystalline 化进程。 structure of pyrolysis char has been analyzed simultaneously in this paper. The results indicate that coal preparation has a 关键词：洗选；结构；热解；煤焦；灰 notable impact on the ash content of coal and little effect on the 0 引言 microcrystalline structure and macromolecular structure of coal. On a micro level, it was found that coal preparation led to the 长期以来，我国的能源消费结构以煤炭为主， decrease of aliphatic hydrogen-enriched degree and the ratio of 由于我国煤炭煤质较差，灰分和硫含量相对较高[1]， aliphatic hydrocarbon and aromatic h