流化床内油页岩半焦燃烧过程孔隙特性分析.pdfVIP

第 28 卷 第 35 期 中 国 电 机 工 程 学 报 Vol.28 No.35 Dec. 15, 2008 14 2008 年 12 月 15 日 Proceedings of the CSEE ©2008 Chin.Soc.for Elec.Eng. 0258-8013 (2008) 35-0014-07 TQ 522 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 流化床内油页岩半焦燃烧过程孔隙特性分析 秦宏，孙佰仲，王擎，周明正，刘洪鹏，李少华 ( 东北电力大学能源与机械工程学院，吉林省 吉林市 132012) Analysis on Influence Factors of the Characteristic of Pore Structure During Combustion of Oil Shale Semi-coke QIN Hong, SUN Bai-zhong, WANG Qing, ZHOU Ming-zheng, LIU Hong-peng, LI Shao-hua (School of Energy and mechanical engineering, Northeast Dianli university, Jilin 132012, Jilin Province, China) ABSTRACT: Combustion experiments with semi-coke of 大；一次加料量影响孔隙生成的进程，但不会改变灰样的最 Huadian and Wangqing oil shale were conducted in a 终孔隙结构；较大风速和较小半焦粒径，都容易破坏孔结构。 bench-scale FBC reactor. Ash samples were obtained under 关键词：油页岩；半焦；流化燃烧；孔隙结构；分形维数 different combustion conditions. Adsorption isotherms were determined by Micromeritics Gemini 2380 specific area 0 引言 analyzer under nitrogen atmosphere. The pore size distribution 随着各国工业的迅速发展，石油消耗越来越大。 of samples was determined on the basis of BJH theory. 油页岩是一种富含有机物的沉积岩，其资源量储量 Influence factors on pore structure of ash, such as different 十分丰富且分布集中，具有作为接替能源的巨大潜 semi-coke, bed temperature, particle size, apparent fluidized velocity and batch feeding quantity of the above-mentioned 力和有利条件[1] 。实践证明，围绕油页岩“炼油–发 semi-coke were investigated. The result shows that pore 电–