水热合成纳米Bi_2WO_6粉末和其可见光催化活性.pdfVIP

中国环境科学 2008,28(3) ：242~245 China Environmental Science 水热合成纳米Bi WO 粉末及其可见光催化活性 2 6 * 姚三丽,陈建林 ,王仪春 (南京大学环境学院,污染控制与资源化研究国家重点实验室,江苏 南京 210093) 摘要：以Bi(NO ) ⋅5H O 和 Na WO ⋅2H O 为原料,水热合成纳米光催化剂 Bi WO 粉末.以偶氮染料直接耐酸大红4BS 为目标污染物,通过 3 3 2 2 4 2 2 6 XRD 、TEM、BET 和 UV-vis DRS 等表征手段,考察了水热温度、反应物 pH 值以及煅烧对催化剂的可见光催化活性、晶型、粒径和比表 面积等方面的影响.结果表明,140℃和原始 pH 值为 0.57 时水热合成的催化剂颗粒分散均匀,光催化效果最好,在光照 150min 后,对 4BS 的 去除率为 99.9%,其吸收边带达到 470nm 左右,带隙能约为 2.7eV. 关键词：Bi WO ；水热合成；光催化 2 6 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2008)03-0242-04 Hydrothermal preparation of Bi WO nano-powders as visible-light-driven photocatalysts. YAO San-li, CHEN 2 6 * Jian-lin , WANG Yi-chun (State Key Laboratory of Pollution Control and Resouce Reuse, School of the Environment, Nanjing University, Nanjing 210093, China). China Environmental Science, 2008,28(3)：242~245 Abstract ：Visible-light-driven Bi WO photocatalysts were prepared by hydrothermal method. The effects of preparation 2 6 and treatment methods on the structures and catalytic properties of Bi WO photocatalyst were evaluated by the 2 6 degradation of aqueous 4BS at room temperature under visible light irradiation. The obtained powders were characterized by XRD, TEM, BET and UV-vis spectroscopy. Bi WO , hydrothermally synthesized at 140℃ and initial pH 0.57 under 2 6 ultrasonic dispersion exhibited the highest photocatalytic activity due to the good crystallization and high specific surface area. The removal of 4BS was 99.9% ofter illumination 150min. Key words ：Bi WO ；hydrothermal preparation ；photocatalysis 2 6 近年来,利用半导体光催化技术降解废水及