第一煉鋼極低磷鋼種煉製製程開發.docVIP

微裂縫石材奈米補強處理研究* A Study of Nano-repairing for Micro Fissures of Stones* 郭 志 成1 ■ 邱 孟 君2 ■ 黃 菽 菡3 ■ 蘇 裕 翔4 J. C. Kuo 1 M.C. Chiu 2 S.H. Huang 3 Y.H. Su 4 九十七年十月二十三日在本會九十七年年會宣讀之論文 財團法人石材暨資源產業研究發展中心石礦資源組　1組長　2助理研究員　3研究助理 化石類石材屬於沈積岩，常有許多裂縫與孔洞，造成加工時斷裂和破損。雖然目前業者以環氧樹脂補強石材裂縫與孔洞，使其足以承受切割與研磨等加工，但石材表面仍有微裂縫出現，影響石材行銷品質。本研究乃以添加不同比例矽溶膠的環氧樹脂，施作在具有大量微裂縫的化石類石材－莫尼卡，比較其與未補強處理和僅用環氧樹脂處理後的機械強度、防污性和耐黃變性。研究結果顯示莫尼卡石材經補強處理後，其彎曲強度明顯提升，但抗壓強度和耐黃變性則與補強的環氧樹脂和所含的奈米矽溶膠添加量無明顯關係。此外，以奈米膠材處理者具有較佳的防污能力。最後，該奈米膠材應用於黑金峰等微裂縫石材補強，達到表面平整且高光澤度的目標，證實矽溶膠修補微裂縫石材的果效。 關鍵詞： 微裂縫、石材、奈米膠材、矽溶膠 Fossil stone, a sedimentary rock, usually breaks to pieces during processing because of its many fissures and porous holes. Stone factories often fill the fissures and holes with epoxy resin so the fossil stones can better sustain the cutting and polishing. The final products are still blemished by some micro fissures which affect the sales of these products. The purpose of this study was to investigate the nano- repairing using epoxy resin mixed with a varying amount of silica sol. Molica fossil stone was selected for this experimental study. The mechanical strength, stain resistance and non-yellowing property of repaired Molica were compared with that of unrepared Molica or Molica repaired with the common epoxy resin. Results showed that the flexural strength of repaired Molica evidently increased, but the compressive strength and non-yellowing property stayed the same regardless of the epoxy resin and silica sol. The stones when treated with epoxy resin/silica sol had a better stain resistance. When Brecha Maron is treated with epoxyresin/silica sol nanorepairing, the product displayed a smooth and glossy surface. This study verified that the silica sol nano-repairing is effective for the fossil stones. Key words: micro fissure, stone, nanoglue, silica sol 壹、前　言 天然石材因具有特殊的紋路與色澤，一直深受建築師和消費者的青睞，在建築市場佔有一席地位。隨著世界石材礦產不斷開發，新品種石材陸續問世，更促進建築師和消費者的熱愛，尤其近年來，大理石和化石憑藉柔和的色彩和紋路，擄獲室內設計師和消費者的心，在國內建築市場興起，逐漸與花崗石並駕齊驅。然而細探石材的成因與結構，發現不同石材因成形原因不