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次世代変性溶液重合sbr
Modified Solution SBR for the Next Generation
Masahiro Shibata Takuo Sone Toshihiro Tadaki Akihiko Morikawa
In recent years, the reduction of rolling resistance of tires has become more significant in the tire in-
dustry because it has close relation to the fuel consumption efficiency and CO emission of motor vehicles.
Rolling resistance is primarily related to the hysteresis loss in the tire tread compounds and silica has been
widely used owing to its lower hysteresis nature than that of carbon black. New concept of styrene butadi-
ene copolymers polymerized in solutionS-SBRswhich can strongly interact with silica has been proposed
to reduce rolling resistance. Various S-SBRs having two different functional groups were polymerized and
the viscoelastic properties of their compounds were measured. S-SBRs that have both amino group and alk-
oxysilyl group showed superior improvement on hysteresis loss property in silica compound compared to
that of only alkoxysilyl group. This new class of S-SBRs also showed excellent mechanical properties and
abrasion resistance because of the strong interaction with silica and the resulting improvement of silica dis-
persion.
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