高分子材料研究方法核磁共振与电子顺磁共振波谱法祥解.ppt

3.4.2 Instrumentation Sampling Widely used spin traps Nitroxides Forming free radicals of nitroxides 3.4.3 Elucidation of EPR Spectra EPR Spectra Horizontal axis: the field intensity Vertical axis: The relative absorbance: The differential of the relative absorbance: 3.4.3 Elucidation of EPR Spectra Hyperfine Structure (HFS): interactions between unpaired electrons and nuclei Dipole-dipole interaction: anisotropic 3.4.3 Elucidation of EPR Spectra Hyperfine Structure (HFS): Interaction of Fermi contact: Electrons in s orbitals: isotropic interaction Free