基于氮气吸附法的渝东南下寒武统页岩孔隙的分形特征.pdfVIP

科技导报2014，32（19） 基于氮气吸附法的渝东南下寒武统基于氮气吸附法的渝东南下寒武统 页岩孔隙的分形特征页岩孔隙的分形特征 熊健，梁利喜，刘向君 西南石油大学油气藏地质及开发工程国家重点实验室，成都610500 摘要摘要 分形维数是多孔介质不规则程度的度量，以渝东南下寒武统页岩的氮气吸附法测量结果为研究对象，采用FHH模型的分 形维数计算方法，得到渝东南下寒武统页岩的分形维数。研究结果表明，渝东南下寒武统页岩孔隙的分形维数具有明显孔径分 界点，即具有双重分形特征，小孔隙分形维数D 变化范围在2.3559~2.6577，平均值为2.488，大孔隙分形维数D 变化范围在 1 2 2.5971~2.8746，平均值为2.7631；大孔隙分形维数的平均值大于小孔隙分形维数的平均值，说明大孔隙结构的复杂程度大于小 孔隙结构的复杂程度；页岩孔隙的分形维数与有机碳（TOC）含量、吸附气量、比表面积和孔容呈正相关，其中与孔隙的比表面积 和孔容的相关性显著，而与黏土矿物含量呈弱负相关。 关键词关键词 渝东南；页岩；分形维数；氮气吸附法；双重分形 中图分类号中图分类号 TE328 文献标志码文献标志码 A doidoi 10.3981/j.issn.1000-7857.2014.19.008 Fractal Characteristics of Pore Structure of Lower Cambrian ShaleinSoutheastChongqingUsingNitrogenAdsorptionData XIONGJian,LIANGLixi,LIUXiangjun StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,SouthwestPetroleumUniversity, Chengdu610500,China AbstractAbstract ThefractaldimensionsofporestructureofshaleinthesoutheastChongqingarecalculatedusingtheFHHmodelbasedon measuredresultsoftheporestructurebynitrogenadsorption.Theresultshowsthatthefractaldimensionsofporestructureofshalein the southeast Chongqing obviously have the aperture boundary point, that is to say, have the dual fractal feature. The fractal dimensionvaluesofthebigporestructureare 2.3559-2.6577,withanaverageof 2.488,andthefractaldimensionvaluesofthesmall porestructureare 2.5971-2.8746,withanaverageof 2.7631.Thesmallporestructure,withalargerfractaldimensionvalue,showsa higherdegreeofcomplexitythanthelargeporestructure.Thereisapositivecorrelationamongthefractaldimensionvaluesofshale pore structure and TOC content, gas adsorption, specific surface area and pore volume. Especially, it is found that the fractal dimensionvaluesshowasignificantlypositivecorrelationwiththespecificsurfaceareaandporevolume.Whereas,thereisanegative correlationbetweenthefractaldimensionval