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AZeoliteImidazolateFrameworkZIF-8CatalystforFriedel-CraftsAcylation.pdf

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AZeoliteImidazolateFrameworkZIF-8CatalystforFriedel-CraftsAcylation.pdf

2012 Chinese Journal of Catalysis Vol. 33 No. 4 Article ID: 0253-9837(2012)04-0688-09 DOI: 10.1016/S1872-2067(11)60368-9 Article: 688–696 A Zeolite Imidazolate Framework ZIF-8 Catalyst for Friedel-Crafts Acylation * Lien T. L. NGUYEN, Ky K. A. LE, Nam T. S. PHAN Department of Chemical Engineering, Hochiminh City University of Technology, VNU-HCM, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City 740128, Viet Nam Abstract: A zeolite imidazolate framework, ZIF-8, was synthesized and characterized by dynamic laser light scattering, X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, Fourier transform infrared, atomic absorption spectrophotometry, and nitrogen adsorption measurements. The ZIF-8 was highly crystalline and porous with a surface area of 2 over 1600 m /g. Friedel-Crafts acylation of anisole and benzoyl chloride proceeded well in the presence of ZIF-8 (2–6 mol%) without the need for an inert atmosphere. The reaction afforded a selectivity of 93%–95% to the p -isomer. The solid catalyst can be separated from the reaction mixture by simple centrifugation and reused without significant degradation in catalytic activity. There was no leaching of active acid species into the reaction solution. Key words: imidazolate framework; zeolite imidazolate framework ZIF-8; Friedel-Crafts acylation; porous material; catalysis CLC number: O643 Document code: A Re