【参考】固相配位反应及配合物的性质表征.docVIP

固相配位反应及配合物性质表征 摘要： 本实验研究的是固相反应和固相化合物的表征，在室温下将8-羟基喹啉与一水醋酸铜（物质的量比2：1），在研钵中充分研磨，发生固相配位反应。混合物颜色逐渐由蓝变绿最后变为黄绿色，并对配合物进行纯化。用元素分析、IR、TG-DTA对产物进行表征其测定结果表明：配合物的反应级数n=1，活化能kJ/mol,频率因子，速率系数s-1，并有一个未成对电子。 关键词：8-羟基喹啉；醋酸铜；固相反应；表征 Abstract: This study is the solid-phase reaction and solid-phase compounds were characterized at room temperature will be eight one-hydroxyquinoline in acetic acid according to the molar ratio of 2:1 nickel-accurate weighing, grinding in a mortar fully occurred solid-solid state reaction. Mixture after the end of the color change, and to purify the complexes. By Su-analysis, IR, TG-