双语物理化学之统计热力学的应用材料.pptVIP

Justification 20.4 - continued Now we can write As we know, which gives Justification 20.4 - continued In terms of the stoichiometric numbers, we would write We shall illustrate the application of eqn 54 to an equilibrium in which a diatomic molecule X2 dissociates into its atoms: (b) A dissociation equilibrium According to eqn 54 ( with a = 1, b = 0, c = 2, and d = 0): with Where D0 (X-X) is the dissociation energy of the X-X bond. The standard molar partition function of the atoms X are (b) A dissociation equilibrium - continued gX is the degenerac