磷酸钙的溶胶凝胶制备法及应用.ppt

Contents Materials Research Bulletin 41 (2006) 1754–1762 Discussion: Fig6: SEM micrograph of HA powders derived from EDTA route. Discussion: Conclusion Fig8: A flow chart of the sol–gel synthesis of HA powder. Fig9:XRD pattern of the HA nanopowders sintered at 600 ℃. Fig10:Phase composition of the samples sintered at different temperatures 600 ?C, 700 ?C, 800 ?C and 900 ?C. Fig11:TEM micrograph of HA nanopowders sintered at 600 ℃. HA nanopowder with crystallites of 20–30nm size was prepared via a simple sol–gel method. Through appropriate sintering at temperature of 600 ?C, the prepared HA nanopowder exhibited a nanoscale, low-crystallinity, apatitic structure, resembling that of human bone apatite. The crystallinity and morphology of the HA nanoparticles were dependent on the sintering temperature. The crystallinity and crystallite size of the HA nanopowders increase with increasing of sintering temperature. Colloids and Surfaces B: Biointerfaces 57 (2007) 237–242 Table2: Processing parameters of preparing HA films on titanium alloy by sol–gel Fig13: Surface morphologies of the sample N2 (calcinated at 600 ℃, left), N3 (calcined at 700 ℃,middle),and N4 (calcined at 800 ℃,right). Fig14:XRD patterns of the sample N4 (calcinated at 800 ?C, left) and A4(with ammonia in raw material, calcinated at 800 ℃ right) Fig15:Surface morphologies of the sample N4 (calcinated at 800 ?C, left) and A4(with ammonia in raw material, calcinated at 800 ℃ right) The addition of ammonia can increase the HA content in the films and the sol–gel film is more compact and continuous.. When the final heat treatment temperature is below 500 ℃, the films did not stabilize and were easily deliquesced. With increasing the calcinating temperature, the structure of the film becomes more compact and changes from granule and lamellar to cellular structure and the Ca/P ratio of the films has a slightly increase because of the loss of P in th