互穿网络聚合物材料.pptVIP

* Enhanced Ionic Conductivity of Semi-IPN Solid Polymer Electrolytes Based on Star-Shaped Oligo(ethyleneoxy) cyclotriphosphazenes By Kangbin Lin Macromolecules 2012, 45, 7931 ?7938 Dan He, Song Yun Cho Dong Wook Kim, Changjin Lee, and Yongku Kang* Contents Introduction Synthetic routes Results and discussion Conclution * * Introduction All-Solid-State Lithium Ion Battery Higher safety Higher energy density Wider operating temperature Long service life Glassy sulfide electrolyte PEO based polymer electrolyte LiPON thin film electrolyte * Introduction Migration mechanism of lithium ions PEO and its derivatives based polymer electrolyte Low cost Good chemical stability Sufficient flexibility Low size and weight Low ionic conductivity High crystallinity * Synthetic routes R R R R R R Cyclotriphosphazenes (环三磷腈) Ethyleneoxy groups Vinyl/Acryl groups Ionic conductivity Network structure High ionic conductivity (Plasticizers) (Cross-linker) Sufficient mechanical strength High flame resistance Chemical and thermal stability * Synthetic routes Star-Shaped Cyclophosphazene Plasticizers Liquid or gel-like material * Synthetic routes Star-Shaped Cyclophosphazene Cross-Linker * Synthetic routes Schematic Structure of Semi-IPN SPE Cross-linker(PA6) Plasticizer(PMEn) Lithium salt Thermal initiator In situ radical polymerization * Synthetic routes Formation of semi-IPN SPE The semi-IPN SPE film 30 wt% of PA6 and 70 wt% of PMEn with LiSO3CF3, [EO]/[Li+] = 15 * Results and discussion Temperature dependence The effect of the molecular weight DSC thermograms of the SPEs 30 wt% of PA6 and 70 wt% of PMEn with LiSO3CF3, [EO]/[Li+] = 15 The number of EO units * Results and discussion [EO]/[Li+] ratio * 30 wt% of PA6 and 70 wt% of PMEn with LiSO3CF3, [EO]/[Li+] = 15 * Results and discussion Content of the plasticizers Lithium salt LiN(SO2CF3)2 Larger ionic radius * 30 wt% of PA6 and 70 wt% of PMEn [EO]/[Li+] = 15 LiSO3CF3, [EO]/[Li+] = 15 * Results and discussion