储运和操作中英文.docVIP

DELTECH公司技术文件 甲基苯乙烯 – 大量货物储运和操作 在大量储存Deltech的甲基苯乙烯产品（对位甲基苯乙烯/乙烯基甲苯）时的关键问题是如何防止产品的预聚合。此外，在长期储存的过程中也必须注意产品由于氧化反应可以通过声称色素或者形成游离颗粒而被分解。Prevention of preformed polymer is the greatest concern when storing Deltech methylstyrenes (para Methylstyrene/Vinyl Toluene) in bulk quantities. In addition, oxidation can cause degradation of product quality by color formation or free particle formation during long-term storage. 甲基苯乙烯（MS）储存过程中的聚合会降低产品的性能，并且会在大部分的应用中造成麻烦。正确的储运管理方式可以保证产品使用时仍然保持优异的性能。Deltech MS在合适的条件下可以安全的在较长时间内储存。理解该产品的聚合特征、储存设备的维护和适当的MS聚合抑制剂的使用等综合因素的调用会对良好的储存MS产品大有裨益。 The formation of polymer in stored methylstyrene (MS) will generally degrade the product quality and prevent use in most applications. Practice of proper inventory management is required to insure the product quality is maintained until product is used. Deltech MS can be safely stored for extended periods if the proper conditions are maintained. Understanding the polymerization characteristics, maintenance of storage equipment and proper polymerization inhibitor use for MS combine to support good inventory management. 甲基苯乙烯的聚合特性 POLYMERIZATION CHARACTERISTICS OF METHYLSTYRENES 甲基苯乙烯（MS）和其他反应性单体，如苯乙烯单体会发生热引发性自由基团聚合。当被加热的时候，单体的分子会变得不稳定，同时形成反应性的自由基团。该自由基团同另一个MS分子反应形成聚合物链。这个聚合物键会不断的增长直至发生链中止反应或者所有的分子都被反应光。整个聚合反应是放热反应（反应过程放出能量），从而导致液体的温度上升，加速产生更多的自由基团参与更多的反应。MS的聚合是自我进行和自行加速的。一旦反应开始产生能量会迅速的增加聚合的速度和聚合物的生成数量。在大量储藏时，聚合反应会以极快的速度发生将储存液体的温度增加到发出大量的MS蒸汽的地步，造成严重的消防隐患。 Heat initiated free radical polymerization can occur in MS and other reactive monomers such as styrene monomer. When heated, the monomer molecule can become unstable and form a free radical which is a reactive species. The free radical reacts with another MS molecule and starts a polymer chain. The chain grows in length until some type of chain terminating event occurs or until all molecules are reacted. The polymerization reaction is exothermic (energy is produced by the reaction) which causes the temperature of the bulk liquid to increase a