“焊接”碳原子的艺术精要.pptx

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“焊接”碳原子的艺术 ——2010年诺贝尔化学奖成果简介 目录 01 02 03 Profiles Ei-ichi Negishi Prize share: 1/3 Richard F. Heck Prize share: 1/3 Akira Suzuki Prize share: 1/3 The Nobel Prize in Chemistry 2010 was awarded jointly to Richard F. Heck, Ei-ichi Negishi and Akira Suzuki for palladium-catalyzed cross couplings in organic synthesis. Richard F. Heck Born :In Springfield, Massachusetts, U.S.A. on August 15, 1931 Family background: he’s a son of a housewife and a salesman, and they moved to Los Angeles, California at his age of eight. Richard F. Heck Learning and woking experiences: His early teens: In 1952: In 1954: In 1955: returned to UCLA In 1956: work for the Hercules Powder Co. In 1971: left Hercules and accepted a faculty(全职教员 )position at the University of Delaware (特拉华州) In 1989:retired from UD Now:live in Philippines with his wife Heck in University of Delaware Heck and his wife From Richard F. Heck His passion for chemistry began in his early teens His interest developed throughout high school and culminated(达到极点) in his majoring in Chemistry at the UCLA. Heck was drawn to the complexity (复杂性)and versatility(易变 )of the area and particularly enjoyed the way you can make all sorts of compounds“ Heck continued his research on neighboring group effects(邻基效应) when he came back to UCLA from Swiss. In Swiss ,Although Heck accomplished “little of scientific value in the two years that I was in this program”?the experience he gained in transition(过渡) metal chemistry would prove to be invaluable (极大意义的)in his next project His breakfast in chemistry Richard F. Heck And his Lunch Background of organotransition metal chemistry Heck’s first work Significance of his work Richard F. Heck And also his Lunch His discussion with his colleague His first experiment ----This is his next move Richard F. Heck Richard F. Heck in the laboratory From Richard F. Heck And also his Lunch Advantages and drawbacks of his find A:Compatibility(通用性) D:The use of highly to

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