超细cu粉对储氢合金电极电化学性能的影响-有色金属工程.docVIP

doi: 10.3969/j.issn.2095-1744.2016.01.004 纳米粉对储氢合金电极电化学性能的影响 (中国有色桂林矿产地质研究院有限公司 国家特种矿物材料工程技术研究中心 广西超硬材料重点实验室，广西 桂林 541004) 摘 要：以直流电弧等离子法制备纳米铜粉，对比不同质量纳米铜粉取代镍粉作为导电剂对储氢电池负极材料AB5型储氢合金电极电化学性能的影响。结果表明，制备的铜粉为近球形颗粒，中粒径为150 nm。采用纳米铜粉取代镍粉作为导电剂后，可以显著改善储氢合金负极的充放电性能和高倍率性能，在1 800 mA/h的放电电流密度下，以纳米铜粉替代50%的镍粉作为导电剂，高倍率从7.65%提高至44.18%。纳米铜粉的电催化活性不如镍粉，但可以显著提高合金电极的导电性，改善动力学性能。 关键词： 中图分类号：TF123.72; TG113.2 文献标志码：A 文章编号：2095-1744(201)01-0000-00 Effect of Cu Nano-Particles on Electrochemical Properties of Hydrogen Storage Alloy Electrode QIN Hai-qing, LIU Wen-ping, LIN Feng, ZHANG Zhen-jun, ZHANG Jian-wei, LEI Xiao-xu (National Engineering Research Center for Special Mineral Material, Guangxi Key Laboratory of Superhard Material, China Nonferrous Metal (Guilin) Geology and Mining Co. Ltd., Guilin, Guangxi 541004, China) Abstract: The Cu nano particles are prepared by direct current arc plasma evaporation method, and the effects of the substitution of the different quantity Cu nano particles for the Ni powder as conductive agent on the electrochemical performance of the materials AB5 type hydrogen storage alloy electrode are analyzed. The results show that the obtained Cu power is spheroidal particles and the median particle diameter is 150 nm. The charge/discharge property and high-rate dischargeability of the hydrogen storage alloy electrode is remarkably improved by the substitution of Cu nano particles for Ni powder. When the50% Ni powders are substituted by Cu nano particles, the high rate dischaegeability of the alloy electrode is increased to 44.18% from 7.65% at 1 800 mA/h discharge current density. The electrocatalytic performance of Cu nano particles is inferior to Ni powder, but the electrical conductivity of alloy electrode is increased and kinetics property is improved by using Cu nano particles as conductive agent. Key words: Cu nano particles; Hydrogen storage alloy; Electrochemistry; Conductive agent AB5型储氢合金由于具有电化学容量高、高倍率性能好、记忆效应小、环境污染少等优点已被广泛应用于镍氢电池负极材料[1-3]。近几年来，随着镍