贾洲平毕业论文Ag-AgCl-季铵化壳聚糖_OREC_TiO2复合膜光催化降解有机污染物的研究.docVIP

摘 要 本实验通过研究Ag-AgCl-季铵化壳聚糖/OREC/TiO2复合膜光催化对有机物的降解，光催化具有分解水制氢和光降解有机污染物等作用，在解决能源问题、温室效应和环境问题方面有重要的应用前景， 贵金属一半导体光催化剂结合了贵金属的表面等离子体共振效应和半导体光催化活性的优点，能够提高对可见光的利用率和光催化活性，实验以壳聚糖、二氧化钛累托石为原料先将壳聚糖进行季铵化处理，将TiO2及Ag-AgCl等离子体通过沉积-沉淀法和光化学反应加入有机累托石中，并采用N，N-亚甲基双丙烯酰胺(NMBA)做交联剂进行交联反应，制得了Ag-AgCl-季铵化壳聚糖/OREC/TiO2复合膜；利用X射线衍射(XRD)、透射电子显微镜(TEM),扫描电子显微镜((SEM),X射线光电子能谱分析(XPS)、激光拉曼光谱(Raman),紫外可见漫反射光谱(UV-vis DRS)等测试手段对所制备的催化剂进行了表征。分别以甲基橙和4一硝基苯酚为目标降解物，研究了光催化剂在可见光下对有 机污染物的光催化降解性能，探讨了复合光催化材料的结构与光催化性能之间的关系。通过紫外一可见光光谱分析和活性自由基的分析，探讨了制备的光催化剂对有机污染物的降解机理。 关键词：累托石；；季铵化壳聚糖；光催化；氯化银；等离子体 Abstract This experiment by studying the Ag AgCl - quaternary ammonium chitosan/when/TiO2 composite film photocatalytic degradation of organic matter, photocatalysis has decomposition hydrogen and light degradation of organic pollutants in water, and so on, to deal with the problem of energy, the greenhouse effect and environmental issues have important application prospect, precious metals a semiconductor photocatalyst combines the precious metal surface plasmon resonance effect and the advantages of semiconductor photocatalytic activity, can improve the utilization ratio of visible light and light catalytic activity, the experiment with chitosan, titanium dioxide rectorite as raw material to chitosan quaternary ammonium, TiO2 and Ag AgCl plasma by sedimentary - precipitation and light chemical reactions in organic pareto stone, using N, N - methylene double acrylamide (NMBA) as crosslinking agent of crosslinking reaction, with Ag AgCl - quaternary ammonium chitosan/when/TiO2 composite film; Using X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) analysis, laser Raman spectroscopy (Raman), uv-vis diffuse reflection spectroscopy (UV - vis DRS) of the test methods s