OrganometallicsReceivedMay13,2009AuthorSamuelCastro.pptVIP

Crown Ether Palladacycles as Metalloligands: Suitable Precursors for Tetranuclear Mixed Transition/Non-Transition Metal Complexes Organometallics Received May 13, 2009 Author：Samuel Castro-Juiz,? Alberto Fernandez,? Margarita LopezTorres,?Digna Vazquez-Garcia,? Antonio J. Suarez,? Jose M. Vila,*,? and Jesus J. Fernandez*, ??Departamento de Quimica Fundamental, Universidade da Coruna, E-15071 A Coruna, Spain （西班牙拉科鲁吉亚大学物理化学系） ?Departamento de Quimica Inorganica, Universidad de Santiago de Compostela, E-15782 Santiago de Compostela, Spain（圣地亚哥大学物理化学系） Introduction The particular ability of crown ethers to complex cations has been used to study a large number of applications such as the production of sensors and the selective extraction of cations or the ionic transport in membranes. We can use them to obtain photochemical controlled and electrochemical active receptors or compounds with promising anticancer properties. They may also provide a novel and interesting route to the preparation of metalloligands containing a crown ether ring systems, capable of further coordination to metal cations, producing mixed transition metal/main group metal species. 2,3,4-(MeO)3C6H2C(H)=N-[9,10-(C8H16O5)C6H3] (a): 2,3,4-(MeO)3C6H2C(H)=N[9,10-(C10H20O6)C6H3 (b). 二、Synthesis of the Complexes. [Pd{2,3,4-(MeO)3C6HC(H) =N-[9,10 (C8H16O5)C6H3]-C6,N}(μ-O2CMe)]2 (1a). [Pd{2,3,4-(MeO)3C6HC(H) =N-[9,10 (C8H16O5)C6H3]-C6,N}(μ-O2CMe)]2 (1b). [(2a)Na2(ClO4)2] (6a). [(2a)K2(ClO4)2] (7a). [(2a)(NH4)2(PF6)2] (8a). [(2a)Pb2(SCN)4] (9a). [(1b)K2(ClO4)2] (2b). [(1b)Pb2(SCN)4] (3b). [(1b)Rb2(ClO4)2] (4b). [(1b)Ba2(ClO4)4] (5b). Results and discussion Microanalyses（微量分析） were carried out using a Carlo Erba（卡劳尔巴）elemental analyzer, model 1108. The FAB（快原子轰击） mass spectra were recorded using a FISONS Quatro mass spectrometer with a Cs ion gun; 3-nitrobenzyl alcohol was used as the matrix. IR spectra were recorded as Nujol mulls or polythene discs Nujol mulls or KBr discs on a Perkin-