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HMX的合成与应用研究现状
王波
(中北大学化工与环境学院 太原 030051)
摘 要:HMX是当前使用的军用炸药中能量较高、爆轰性能和热安全性能兼优的高能炸药。本文对传统的醋酐法生产HMX的生产工艺进行了阐述。以高聚物为粘结剂制造的含HMX的塑料粘结炸药(PBX),压制成型后具有能量高、感度低的优点,在工业中的应用日益广泛。由于炸药属于危险品,常用的铆接、焊接、螺栓连接等方式都不适宜于炸药药柱的成型粘接。应用胶接工艺粘接的PBX炸药药柱,其重量轻,应力分布均匀,工艺温度低,效率高,可以制作各种形状的PBX药柱,可满足不同领域对炸药成型的质量要求,这对进一步拓宽PBX的应用领域,具有重要意义。由于粘接的质量与药柱粘接面的胶粘剂的性能有关,本文研究了蒸馏水和甲酰胺对药柱表面的润湿作用,并以此为基础计算了HMX塑料粘结炸药药柱的表面能。几种结构胶粘剂对药柱的粘接试验证明,结构胶粘剂对药柱表面都有一定的粘接强度,胶粘剂的种类、厚度对药柱的爆速有一定的影响。
【】:The HMX Synthesis and Application of Research
Wangbo
(Chemical and Environmental Sciences of the University of North Taiyuan China 030051)
【 Abstract 】 : HMX is a high energy currently used in military explosives, detonation properties, and thermal safety performance is excellent both in high explosives. Traditional acetic anhydride method of production of HMX manufacturing process are described.Manufacture of polymer as binder containing HMX plastic bonded explosives (PBX), the advantages of high energy, a sense of low pressure molding, the increasingly widespread application in industry. Explosives,dangerous goods, the riveting, welding, bolt connections are not suitable for the forming of explosive propellant bonding. Application bonding process bonding of PBX explosives grain, light weight, stress distribution, low process temperature, high efficiency, can make various shapes the PBX grain, which can meet the quality requirements of the different areas of the explosive forming, which isfurther broaden the application areas of the PBX is of great significance. Quality and grain of the adhesive bonding surface of the adhesive performance of distilled water and formamide on the grain surface wetting, as the basis for calculation of HMX plastic bonded explosives grain surface. Several structural adhesives on grain bonding tests proved that the bond strength of structural adhesives on the grain surface has a certain type of adhesive, the thickness of certain grain of explosive speed.
【Keywords】:HMX Acetic anhydride method Bind
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