地沟油生物柴油与石化柴油喷吹还原铜渣中磁性铁的研究.docVIP

地沟油生物柴油与石化柴油喷吹还原铜渣中磁性铁的研究 李建武1，李博1，马保中1,2 (1.昆明理工大学 省部共建复杂有色金属资源清洁利用国家重点实验室，昆明 650093；2.北京矿冶研究总院北京 100160) 摘要：对柴油和地沟油生物柴油还原铜渣中磁性铁的特性进行研究，通过研究柴油和生物柴油高温热解产物分布规律来阐述其对铜渣中磁性铁的还原过程。结果表明还原之后渣中磁性铁含量降低，铁橄榄石相逐渐增多；在还原过程中，液体还原剂首先热解为焦炭、H2、CO和CH4，随后热解产物将渣中的Fe3O4还原成FeO，FeO与游离态的SiO2结合形成铁橄榄石相；与石化柴油相比，地沟油生物柴油对铜渣中磁性铁的还原效果更好，可能是由于地沟油生物柴油高温热解气体产物的产率更高。利用地沟油生物柴油替代铜渣电炉贫化工艺中的柴油作为还原剂是可行的。 关键词：生物柴油铜渣磁性铁贫化高温热解TF803.3；TF811 文献标志码：A 文章编号：1007-7545（2016）10-0000-00 Study on Reduction of Magnetite in Copper Smelting Slag by Injecting Biodiesel from Waste Cooking Oil and Petroleum Diesel LI Jian-wu1, LI Bo1, MA Bao-zhong1,2 (1. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China；2. Beijing General Research Institute of Mining and Metallurgy, Beijing 100160, China) Abstract：Characteristics of magnetite reduction in copper smelting slag by biodiesel from waste cooking oil and petroleum diesel were studied. Distribution of high-temperature pyrolysis product from biodiesel and diesel was investigated to elaborate process of magnetite reduction in copper smelting slag by diesel and biodiesel. The results indicate that magnetite content drops while fayalite content rises after reduction. In process of copper smelting slag reduction, liquid reduction agents first crack into coke, H2, CO and CH4, et al, and fayalite phase is formed by combining SiO2 in copper molten slag and FeO reducted from magnetite by pyrolysis products. Reduction effect of magnetite with biodiesel is better than that of diesel due to production of more reducing gases through pyrolysis. It is feasible to substitute biodiesel to diesel as reductant in process of copper smelting slag reduction in electric furnace. Key words: waste cooking oil; biodiesel; copper smelting slag; magnetite; dilution; high-temperature pyrolysis 全球有80%的铜是通过火法冶炼生产的[1]。与传统的冶炼方法相比，熔池熔炼技术具有产量高、熔炼强度大、燃料消耗量低、原料适应性好、环境友好性强[23]的特点，目前被广泛应用于铜冶炼工业中。然而高氧势的强化冶炼会导致炉渣中磁性氧化铁富集，造成熔渣