AlMg10合金铸造零件表面缺陷成因探析_朱远志.docxVIP

· 372 ·　　　　　　　　　　　　　　　　　　　　铸造Vol.53No.5FOUNDRYMay 2004AlMg10 合金铸造零件表面缺陷成因探析朱远志1,2, 尹志民1, 吴有伍2, 夏运来3, 周宇峰3, 黄继武1(1.中南大学材料科学与工程学院, 湖南长沙 410083 ;2.湖南大学材料学院, 湖南长沙 410012 ; 3.湖南华南光电仪器厂, 湖南常德 415000)摘要 :点蚀等表面缺陷会最终导致铝合金的失效。运用金相、扫描电镜、能谱、光谱以及化学分析等多种手段,研究了 AlM g10 合金零件表面缺陷的形貌和成分。 结果表明, 该零件表面缺陷主要为表面点蚀及皮下气孔。 点蚀主要是因为表层及表面中含有较多的氯、 硫等元素。 讨论了皮下气孔形成的机理, 认为皮下气孔中的夹杂来自熔体中尺寸接近或 小于某一临界尺寸的异质相质点;凹槽形核机制是皮下气孔形核的主要机制, 合金熔体凝固时的收缩为气孔形核和长大提供了驱动力。关键词:铝镁合金;点蚀 ;气孔;分析中图分类号:TG290.6;TG292 文献标识码:A 文章编号:1001-4977(2004)05-0372-04The Analysis of the Surface Defects of the AlMg10 Alloy PartsZHU Yuan-zhi1,2 , YIN Zhi-min1 , WU You-wu2 , XIA Yun-lai3 , ZHOU Yu-feng3 , HUANG Ji-wu1 (1.College of Material Science and Engineering, Zhongnan University , Changsa 410083 , Hu′nan, China;2.Materials College, Hu′nan University , Changsa 410012 , Hu′nan, China;3.Hu′nan Province South China Light Electric Instrumental Factory , Changde 415000 , Hu′nan, China)Abstract :The microstructure and chemical composition of the surface defects of AlMg10 alloy were ana-lyzed by the means of OM , SEM , EDX, chemical analysis (CA)and ICP-AES.The results show the sur-face of the AlMg10 alloy contains two types of defects-pitting corrosion and subsurface blowhole.The pro-cess of the pitting corrosionwas activated and accelerated by the highly contained Cl , S inthe surface and the gas pore of the subsurface.The mechanism of the forming of the subsurface blowhole has also been discussed.The research shows that the concave in the non-metallic inclusions in the Al melt provides a spot for the nucleation of the subsurface blowhole .The size of the non-metallic inclusions is less than a threshold value.The driving forces for the growth of the subsurface blowhole come from the shrinkage of the solidifying melt .Keywords:AlMg10 alloy ;pitting corrosion;blowhole ;analysis　　铝镁铸造合金虽然铸造性能不如铝硅合金优良, 但它却具有较好的耐蚀性能, 因此 , 这一类材料常常 被用在某些需要一定抗腐蚀性能的武器构件上。某厂 铸造的 ZL301 合金部分产品 , 在铸造出来若干天之 后, 表面可见明显的白色腐蚀斑点。经过严格按照该 合金传统的热处理制度进行淬火和时效之后 , 腐蚀斑 点变得更加严重。为了找出造成产品