Bi_1_7_Pb_0_3_Sr_2Ca__省略__10_多晶制备工艺对其电学性.docx

第 44 卷 第 8 期人 工 晶 体 学 报Vol． 44 No． 82015 年 8 月JOUＲNAL OF SYNTHETIC CＲYSTALSAugust，2015Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 多晶制备工艺对 其电学性能影响的研究李东麒1 ，陈清明1 ，高翔2 ，杨盛安1 ，张辉1 ，杨宁1( 1． 昆明理工大学材料科学与工程学院，昆明 650093; 2． 中国科学院大学，北京 101408)摘要: 采用溶胶-凝胶法成功制备了 Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 ( BPSCCO) 粉末，通过优化制备工艺获得了电学性能优 良，转变温度在 114 K 左右的 Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 多晶靶材。利用 X 射线衍射仪测试了样品的物相和结构，并利 用四探针法测试了靶材的电阻-温度曲线。对比了不同螯合剂对溶胶-凝胶法制备 BPSCCO 多晶的影响，发现以葡 萄糖酸为螯合剂克服了传统工艺周期长、pH 难调控的缺点。在此基础上，探究了热处理工艺对 Bi1． 7 Pb0． 3Sr2 Ca2 Cu3 O10 多晶电学性能的影响，得到了其最适预烧温度( 600 ～ 700℃ ) 、烧结温度( 820 ～ 830 ℃ ) 及烧结时间( 48 h) 。关键词: Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 ; 螯合剂; 溶胶-凝胶法; 热处理工艺中图分类号: TQ174; TM26文献标识码: A文章编号: 1000-985X( 2015) 08-2284-06DOI:10.16553/j.cnki.issn1000-985x.2015.08.044Study on the Effect of Preparation Process on the Electrical Properties of Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 PolycrystallineLI Dong-qi1 ，CHEN Qing-ming1 ，GAO Xiang2 ，YANG Sheng-an1 ，ZHANG Hui1 ，YANG Ning1( 1． Faculty of Materials Science and Engineering，Kunming University of Science and Technology，Kunming 650093，China;2． University of Chinese Academy of Sciences，Beijing 101408，China)( Ｒeceived 3 April 2015，accepted 30 June 2015)Abstract: Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10 powder was prepared by sol-gel method，and electrical properties wtih Tc around 144 K were acquired by optimizing the preparation process． The crystalline structure of the sampleswas investigated by X-ray diffraction( XＲD)and the temperature dependence of resistance was measuredusing thestandard four-probe method．Asystematic comparison study of Bi1． 7Pb0． 3 Sr2 Ca2 Cu3 O10polycrystalline prepared by different chelating agents was accomplished．The results show that when glucoseacid ( GA)was employed as chelating agent，thepreparation periodof the polycrystalline was largelyshortened compared with the conventionalsol-gelprocess．Further，the influenceof heattreatmentprocedure on the Bi1． 7 Pb0． 3 Sr2 Ca2 Cu3 O10polycrystalline was also investigated for theoptimalcalcinationtemperature(