----初始成分对梯度硬质合金微观组织及脱_层厚度的影响_史留勇.docxVIP

第 22 卷第 7 期中国有色金属学报2012 年 7 月Vol.22 No.7The Chinese Journal of Nonferrous MetalsJuly 2012文章编号：1004-0609(2012)07-1984-07初始成分对梯度硬质合金 微观组织及脱 β 层厚度的影响史留勇 1, 2，刘义敏 1，张守全 3，黄继华 1，赵兴科 1(1. 北京科技大学 材料科学与工程学院，北京 100083；2. 海南大学 机电工程学院，海口 570228；厦门金鹭特种合金有限公司，厦门 361006)要：采用普通市售中颗粒 Ti(C,N)粉末，以一步烧结法制备脱 β 层梯度硬质合金；利用显微组织分析和图像 分析等手段，研究合金初始成分对其微观组织及脱 β 层厚度的影响规律。结果表明：当 Ti(C,N)含量低于 1.6%(质 量分数)时，随着 Ti(C,N)含量的增加，脱 β 层厚度明显增大，而当 Ti(C,N)含量超过 1.6%时，脱 β 层厚度呈缓慢缩小的趋势；随着钴含量的增加，脱 β 层的厚度迅速增大，但当钴含量达到 10%(质量分数)左右时，在脱 β 层与 芯部的界面处钴相聚集现象严重；总碳含量为 6.51%(质量分数)的合金中 WC 晶粒度较大且呈规则的多边形， 在 1 450 ℃、2 h 梯度烧结工艺下制备的脱 β 层厚度可达 38 μm 左右，而总碳含量为 6.23%的合金中 WC 晶粒度较 小且呈等轴化趋势，同时脱 β 层的厚度仅为 17 μm 左右。关键词：梯度硬质合金；Ti(C,N)；初始成分；脱 β 层；微观组织中图分类号：TF125.3；TG135+.5文献标志码：AEffect of starting composition on microstructure and thickness of cubic carbide free layer in graded cemented carbidesSHI Liu-yong1, 2, LIU Yi-min1, ZHANG Shou-quan3, HUANG Ji-hua1, ZHAO Xing-ke1(1. School of Materials Science and Engineering, University of Science and Technology Beijing,Beijing 100083, China;College of Mechanical and Electrical Engineering, Hainan University, Haikou 570228, China;Xiamen Golden Egret Special Alloy Co., Ltd., Xiamen 361006, China)Abstract: The graded cemented carbides with cubic carbide free layer (CCFL) were fabricated by one-step sintering procedure using Ti(C,N) powder with medium particle size as the raw material, and the effect of starting composition on the microstructure and thickness of CCFL was discussed in detail by scanning electron microscopy and soft Image Tool. The results show that, the thickness of CCFL increases gradually with the increase of Ti(C,N) content when it is lower than 1.6% (mass fraction), whereas the thickness of CCFL decreases slightly with the increase of Ti(C,N) content when it exceeds 1.6%. The thickness of CCFL increases rapidly with the increase of Co content, whereas the Co phases are inclined to aggregate in the border between CCFL and core zone when the cobalt content reaches 10% (mass fraction). Th