碳含量对缺碳硬质合金组织和性能的影响_肖逸锋.docxVIP

第 17 卷第 1 期中国有色金属学报2007 年 1 月Vol.17 No.1The Chinese Journal of Nonferrous MetalsJan. 2007文章编号：1004-0609(2007)01-0039-06碳含量对缺碳硬质合金组织和性能的影响肖逸锋 1, 2, 贺跃辉 1, 丰 平 1, 谢 宏 1, 3 , 张丽娟 1, 黄自谦 1, 黄伯云 1(1. 中南大学 粉末冶金国家重点实验室，长沙 410083；湘潭大学 机械工程学院，湘潭 411105；株洲钻石切削刀具股份有限公司，株洲 412007)要：通过配制不同碳含量的 WC-6Co 缺碳硬质合金，采用 X 射线衍射、光学金相、显微硬度、钴磁和 TRS等分析方法，对比研究碳含量对低压烧结缺碳硬质合金的显微组织和性能的影响。结果表明：碳含量影响合金中η 相的类型、含量、分布、WC 的形状以及合金的性能；Co3W3C 相出现在缺碳程度相对较小的合金中，其含量随 碳含量的增加而增大，而 Co6W6C 相与之相反；合金中的 η 相总量随碳含量的增大而减少；随着缺碳程度的增 加，合金中 η 相的分散均匀性变差，并且 η 相趋向于成大块状；WC 大多呈现多角特征；合金的密度和维氏硬度随着碳含量的增加，先大幅度增加后缓慢减小，碳含量为 5.2%(质量分数)时均出现最大值，合金的钴磁和横向断裂强度随着碳含量的增加而增加。关键词：硬质合金；碳含量；η 相；显微组织中图分类号：TF 125.3; TG 135文献标识码：AEffects of carbon content on microstructure and properties of carbon-deficient cemented carbidesXIAO Yi-feng1, 2, HE Yue-hui1, FENG Ping1, XIE Hong1, 3, ZHANG Li-juan1, HUANG Zi-qian1, HUANG Bai-yun1(1. State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China;School of Mechanical Engineering, Xiangtan University, Xiangtan 411105, China; 3. Zhuzhou Cemented Carbide Cutting Tools Co. Ltd., Zhuzhou 412000, China)Abstract: Effects of carbon content on microstructure and properties of WC-6Co carbon-deficient cemented carbides with carbon content from 5.0% to 5.6% prepared by sinter-HIP were analyzed by X-ray diffractometry, optical microscopy, Vickers hardness analysis, cobalt magnetic analysis, TRS and so on. The results show that, in carbon-deficient cemented carbides, carbon content affects the type, amount and distribution of η phase, WC shape and properties of alloys. Co3W3C phase appears in alloys with relative lower degree of carbon-deficient and whose amount increase with increasing carbon content, whereas Co6W6C phase varies reversely. The total amount of η phase decreases with increasing carbon content. With the increase of degree of carbon-deficient, the homogeneity of η phase distribution decreases, η phase tends to become clump shape and WC mostly maintains multangular character.