chapter2potentiometry.pptVIP

在比较中学习，培养分析问题和总结问题的能力，掌握常用仪器分析方法原理、应用，熟悉仪器结构 理解和记忆相结合 查阅文献资料，参加科学讲座，培养创新精神 了解各仪器的仪器厂商，并对每种仪器的型号做对比 平时成绩40%，包括作业、考勤、提问以及文献报告等 期末考试成绩60% 中国色谱网 中国仪器信息网 中国期刊网 仪器厂商 Agilent Waters Micromass Thermo / Beckman 日立 导津 Finnigan / Nicolet Chapter 2 Electrochemistry § 1 Introduction to electrochemistry For example: Zn ?ZnSO4,(xMol) ??CuSO4, (yMol) ? Cu Anode: Zn Zn2+ + 2e- (3) Cathode: Cu2 + + 2e- Cu (4) (2) Standard reduction potential E0, the superscript zero means the standard state conditions. E0, all solutes are 1 M and all gases are 1 atm, other solids or liquids are pure. Zn(s) ?Zn2+(aq, 1M) ? ?H+(aq, 1M) ?H2(g, 1atm) ?Pt(s) E0cell = E0cathode – E0anode 0.76V=0-E0Zn E0Zn=-0.76V So Zn2+ + 2e- Zn(s) E0Zn=-0.76V -平衡时电极电位（V） -标准电极电位 （V） -分别为电极反应中氧化态和还原态的活度； -为电极反应中的电子得失数 If some substance is water or solid, its concentration is 1; if it is liquid, its concentration is pressure. (4) Classification 2.1 indictor electrode Responds to the change in analyte activity. (1) Metallic Electrodes (a) first kind: a metal wire, mesh, or solid strip that responds to its own cation in solution. eg., Cu/Cu2+, Ag/Ag+…… poor selectivity, easily oxidized, limited pH ranges… (b) second kind: a metal coated with one of its sparingly soluble salts. Responds to the anion of the salt. eg., a silver wire coated with AgCl AgCl(s)+e- Ag(s) + Cl- E=0.222-0.005916log[Cl-] Electrode potential（ 25℃） (c) third kind: use two equilibrium reactions to respond to a cation other than that of the metal electrode. EDTA metal ions? (2) Membrane electrodes ISE Respond selectively to ions by the development of a potential difference across a membrane that separates t